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Synthesis of Conductive ZnO nanopowder co-doped with two element by hydrothermal method

机译:水热法合成两种元素共掺杂导电ZnO纳米粉

摘要

This invention is a zinc oxide nano powder having conductivity by doping the heterogeneous element by hydrothermal method at low temperature It provides a method for manufacturing. The periodic table group 1 in detail, Group 2, Group 1 to 3 of the nitrate precursor (Precursor) and acetate precursor (Precursor) to select as the dopant, used in combination, and a method for manufacturing a conductive zinc oxide nanopowders doped heteroatom Thoreau provided. Zinc nitrate Zinc acetate, and the starting material and Sodium hydroxide, Potassium hydroxide, Ammonium hydroxide, Urea was used as a precipitant. Gallium nitrate, Aluminum acetate, Aluminum nitrate, Indium nitrate, yitrium acetate, yitrium nitrate, silicon acetate, silicon nitrate, Lithium acetate, Sodium acetate, Magnesium nitrate, potassium acetate, strontium nitrate, Calcium acetate, Barium acetate among the disparate elements as a dopant In doping the reaction temperature 80 ~ 150 , Zincite was synthesized on the single conductive ZnO nanopowder. In the form of particles, it indicates the size of 80 ~ 250 nm in plate-like or flake-like. In addition, needle-shaped and plate using a pH change by the addition of an inorganic acid of hydrochloric acid wherein the pH adjusting agent and precipitating agent can be controlled in the form of a rectangle. The electrical conductivity properties than conventional zinc oxide is doped ZnO was very good in heterogeneous elements. ;
机译:本发明是通过在低温下通过水热法对异质元素进行掺杂而具有导电性的氧化锌纳米粉末,其提供了一种制造方法。周期表第1组,第2组,第1〜3组的硝酸盐前体(Precursor)和乙酸盐前体(Precursor)中选择作为掺杂剂组合使用,以及制备导电性氧化锌纳米粉掺杂杂原子的方法梭罗提供。硝酸锌乙酸锌和原料以及氢氧化钠,氢氧化钾,氢氧化铵,尿素用作沉淀剂。硝酸镓,醋酸铝,硝酸铝,硝酸铟,醋酸钇,硝酸钇,醋酸硅,硝酸硅,醋酸锂,醋酸钠,硝酸镁,醋酸钾,硝酸锶,醋酸钙,醋酸钡掺杂在反应温度为80〜150℃时,在单根导电ZnO纳米粉上合成了锌矿。呈颗粒形式,指示板状或片状的大小为80〜250 nm。另外,通过添加盐酸的无机酸来改变pH的针状板可以将pH调节剂和沉淀剂控制为矩形。导电性能比常规的氧化锌掺杂的ZnO在异质元素中非常好。 ;

著录项

  • 公开/公告号KR101289044B1

    专利类型

  • 公开/公告日2013-07-23

    原文格式PDF

  • 申请/专利权人

    申请/专利号KR20120003867

  • 申请日2012-01-12

  • 分类号C01G9/02;H01B1/02;B82B3/00;

  • 国家 KR

  • 入库时间 2022-08-21 16:24:48

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