首页> 外国专利> PLATINUM/RUTHENIUM CATALYST FOR DIRECT METHANOL FUEL CELLS

PLATINUM/RUTHENIUM CATALYST FOR DIRECT METHANOL FUEL CELLS

机译:直接甲醇燃料电池用铂/钌催化剂

摘要

The invention relates to a carbon-supported PtRu anode catalyst for direct methanol fuel cells (DMFC) which has a platinum/ruthenium content in the range from 80 to 98 wt. %, preferably in the range from 85 to 98 wt. %, particularly preferably in the range from 85 to 95 wt. % (based on the total weight of the catalyst), on a carbon-based electrically conductive support material and has a mean particle size of less than 3 nm. The catalyst is prepared using a carbon black support material having a specific surface area (measured by the BET method) in the range from 1000 to 2000 m2/g by means of a reduction process using chemical reducing agents with addition of organic acids. Electrodes and membrane-electrode units containing the catalyst according to the invention having a high precious metal loading have an electrode layer thickness of less than 80 m at a PtRu loading per unit area of the electrode of from 6 to 12 mg of PtRu/cm2 and lead to improved electric power in direct methanol fuel cells.
机译:本发明涉及用于直接甲醇燃料电池(DMFC)的碳负载的PtRu阳极催化剂,其铂/钌含量为80-98重量%。 %,优选在85至98重量%的范围内。 %,特别优选在85至95wt。%的范围内。 %(基于催化剂的总重量),基于碳的导电载体材料,并且具有小于3nm的平均粒度。使用比表面积(通过BET法测量)在1000至2000m2 / g范围内的炭黑载体材料,通过使用化学还原剂并加入有机酸的还原方法来制备催化剂。包含根据本发明的催化剂的具有高贵金属负载量的电极和膜电极单元在电极的每单位面积的PtRu负载量为6-12 mg PtRu / cm2时电极层厚度小于80 m。导致直接甲醇燃料电池的电力得到改善。

著录项

  • 公开/公告号KR101229400B1

    专利类型

  • 公开/公告日2013-02-05

    原文格式PDF

  • 申请/专利权人

    申请/专利号KR20077003949

  • 申请日2005-08-13

  • 分类号B01J23/40;B01J21/18;B01J23/46;B01J23/42;

  • 国家 KR

  • 入库时间 2022-08-21 16:25:46

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