首页> 外国专利> SELF-PHOTO INITIATING SILICON ACRYLATE RESIN WITH EXCELLENT FLOWABILITY, DISPERSITY, WEATHERABILITY, FLEXIBILITY, AND SURFACE PHYSICAL PROPERTIES, A MANUFACTURING METHOD THEREOF, AND A UV-CURABLE RESIN COMPOSITION CONTAINING THE SAME

SELF-PHOTO INITIATING SILICON ACRYLATE RESIN WITH EXCELLENT FLOWABILITY, DISPERSITY, WEATHERABILITY, FLEXIBILITY, AND SURFACE PHYSICAL PROPERTIES, A MANUFACTURING METHOD THEREOF, AND A UV-CURABLE RESIN COMPOSITION CONTAINING THE SAME

机译:具有良好的流动性,分散性,耐候性,柔韧性和表面物理性能的自光引发丙烯酸硅树脂,其制造方法以及包含相同成分的可紫外线固化的树脂组合物

摘要

PURPOSE: A self-photo initiating silicon acrylate resin composition is provided to have excellent surface physical properties and hardening rate by remarkably improving hardening reactivity of a self-photo initiating resin.;CONSTITUTION: A UV-curable resin composition comprises: 1-10 weight% of self-photo initiating silicone acrylate resin; 20-70 weight% of one or more oligomers selected from polyester acrylate, urethane acrylate, epoxy acrylate, silicon acrylate, and a mixture thereof; 20-70 weight% of acrylic monomer, and 5-30 weight% of polyfunctional mercaptane. A manufacturing method of the self-photo initiating silicon acrylate resin comprises: a step of mixing a polyfunctional silicon acrylate Michael acceptor and a beta-dicarbonyl Michael donor with an organic solvent in a molar ratio of 0.05-3:1; and a step of conducting a Michael donor addition reaction under the presence of strong acid.;COPYRIGHT KIPO 2013
机译:用途:提供一种自光引发丙烯酸硅树脂组合物,通过显着提高自光引发树脂的固化反应性,使其具有优异的表面物理性能和固化速率。组成:一种可紫外线固化的树脂组合物,包含:1-10重量% %的自光引发硅丙烯酸酯树脂; 20-70重量%的一种或多种选自聚酯丙烯酸酯,氨基甲酸酯丙烯酸酯,环氧丙烯酸酯,丙烯酸硅及其混合物的低聚物; 20-70重量%的丙烯酸单体,和5-30重量%的多官能硫醇。该自光引发丙烯酸硅树脂的制造方法包括:将多官能丙烯酸硅迈克尔受体和β-二羰基迈克尔供体与有机溶剂以0.05-3:1的摩尔比混合的步骤; ;以及在强酸存在下进行迈克尔供体加成反应的步骤。; COPYRIGHT KIPO 2013

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