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ROSIN-BASED NON-IONIC SURFACTANT AND PREPARATION AND USE THEREOF

机译:松香基非离子表面活性剂及其制备与使用

摘要

A rosin-based non-ionic surfactant and the preparation and use thereof. The rosin-based non-ionic surfactant is obtained by the steps of reacting rosin with a dienophile agent in a Diels-Alder addition reaction (S01) to obtain a modified rosin; subjecting the modified rosin to an esterification reaction (S02) with a fatty alcohol or a polyhydroxy alcohol mono fatty acid ester of and to obtain a modified rosin derivate; subjecting the modified rosin derivate to an esterification reaction (S03) with a polyethylene glycol or polyoxyethylene-polyoxypropylene block co-polymer so as to obtain a viscous liquid or waxy solid which has a total active substance of ≥95% and a critical micelle concentration of 1.3×10-4g/ml-6.8×10-3g/ml. The surfactant is suitable for preparing a pesticide emulsifiable solution.
机译:松香类非离子表面活性剂及其制备和用途。所述松香类非离子表面活性剂是通过在Diels-Alder加成反应(S01)中使松香与亲双烯体试剂反应而得到的改性松香的步骤而得到的。使改性的松香与脂肪醇或多羟基醇单脂肪酸酯进行酯化反应(SO 2),得到改性的松香衍生物。使改性的松香衍生物与聚乙二醇或聚氧乙烯-聚氧丙烯嵌段共聚物进行酯化反应(SO3),以获得总活性物质≥95%且临界胶束浓度为5%的粘稠液体或蜡状固体。 1.3×10 -4 g / ml-6.8×10 -3 g / ml。该表面活性剂适用于制备农药乳化液。

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