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ORGANIC MOLECULE (SCHIFF BASE MOLECULE)-INCLUDING FIBROUS ALUMINA SELF-SUPPORTING MEMBRANE AND METHOD OF MANUFACTURING THE SAME, AND DETECTION METHOD/RECOVERY METHOD FOR TRANSITION METAL ION IN WATER WITH THIS COMPOSITE MEMBRANE
ORGANIC MOLECULE (SCHIFF BASE MOLECULE)-INCLUDING FIBROUS ALUMINA SELF-SUPPORTING MEMBRANE AND METHOD OF MANUFACTURING THE SAME, AND DETECTION METHOD/RECOVERY METHOD FOR TRANSITION METAL ION IN WATER WITH THIS COMPOSITE MEMBRANE
PROBLEM TO BE SOLVED: To provide an organic molecule (Schiff base molecule)-including composite and a method of its manufacturing, and detection method/recovery method for transition metal ions in water using this composite.;SOLUTION: This composite comprises an organic molecule (Schiff base) and alumina nano particles having an aspect ratio of 30-5,000, and the specific surface area and pore volume of the composite are not greater than 10 m2/g and not greater than 0.01 cm3/g respectively, compared with those of the self-supporting membrane before including the organic molecule, not smaller than 100 m2/g and not smaller than 0.05 cm3/g, respectively. In this method of manufacturing an organic molecule-including composite, the organic molecule-including composite and fibrous alumina self-supporting membrane of various forms are heated and dehydrated, and the organic molecule is vaporized in a vacuum environment and it is adsorbed and filled up in the slit-like pore at a high density and uniformly in the entire composite. The detection method/recovery method for transition metal ions are also provided and the composite is useful for the detection method for transition metal ions, for example, transition metal ions dissolved in water.;COPYRIGHT: (C)2013,JPO&INPIT
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机译：解决的问题：提供包含有机分子（席夫碱分子）的复合物及其制造方法，以及使用该复合物的水中过渡金属离子的检测方法/回收方法。 （席夫碱）和长径比为30-5,000的氧化铝纳米颗粒，复合材料的比表面积和孔体积不大于10 m 2 / g并且不大于0.01 cm 3 / g，与包含有机分子之前的自支撑膜相比，不小于100 m 2 / g，不小于0.05 cm 3 / g。在这种包含有机分子的复合材料的制造方法中，将包含有机分子的各种形式的复合材料和纤维状氧化铝自支撑膜加热并脱水，然后在真空环境下将其蒸发并吸附并填充。在缝状孔中高密度且均匀地分布在整个复合材料中。还提供了过渡金属离子的检测方法/回收方法，该复合材料可用于过渡金属离子的检测方法，例如溶于水中的过渡金属离子。;版权所有：（C）2013，JPO＆INPIT
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