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One-Pot Synthesis of Chiral Amino acid Schiff-base Dinuclear Complexes and Their Selective Aqueous Sensing of Salts and Ions
One-Pot Synthesis of Chiral Amino acid Schiff-base Dinuclear Complexes and Their Selective Aqueous Sensing of Salts and Ions
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机译:一锅法合成手性氨基酸席夫碱双核配合物及其对盐和离子的选择性水感测
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摘要
PURPOSE: A method for preparing a chiral amino acid Schiff-base dinuclear complex is provided to ensure excellent solubility and to use the complex as a chemical sensor material. CONSTITUTION: A chiral amino acid Schiff-base dinuclear complex contains a chiral amino acid Schiff base which selectively senses salts and ion in an aqueous solution. Compounds selectively sensing salts and ions are Zn_2(slys)_2Cl_2 compound(1), Na_2Cu(S-lys)_2(H_2O)_2(ClO_4)_2 compound(2), or Cu(SornH)_2(H_2O)_2(ClO_4)_2 compund(3). A method for preparing the chiral amino acid Schiff-base dinuclear complex comprises: a step of preparing the compounds(1)(2)(3); and a step of measuring the crystalline structure and sensing performance of the compounds.
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