首页> 外国专利> METHOD FOR SINGLE CRYSTALS GROWING OF SOLID SOLUTIONS OF COPPER BROMIDE- IODIDE PENTATHIOPHOSPHATE Cu6PS5 (Br0,5I0,5) BY CHEMICAL TRANSPORT REACTIONS

METHOD FOR SINGLE CRYSTALS GROWING OF SOLID SOLUTIONS OF COPPER BROMIDE- IODIDE PENTATHIOPHOSPHATE Cu6PS5 (Br0,5I0,5) BY CHEMICAL TRANSPORT REACTIONS

机译：化学转移反应制备单溴化铜-碘化五磷酸铜Cu6PS5（Br0,5I0,5）固溶体的方法

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摘要

The invention relates to the field of inorganic chemistry. A method for single crystals growing of solid solutions of copper chloride-bromide pentathiophosphate CuPS(BrI) by chemical transport reactions includes stepped heating the vacuumized quartz ampoules containing the initial components in the prescribed stoichiometric ratio, to the maximum temperature and holding them at the same temperature within 24 hours and further growth of single crystals. Basic: copper, phosphorus and sulfur and binary: copper bromide CuBr and copper iodide CuI are used as initial components for synthesis, at that the maximum synthesis temperature is 943 ± 5 K, and the growing is carried out with the use of stoichiometric mixture of CuBr / CuI as transporting agent at the rate of 20 mg/smof vial free volume. The use of the invention allows to simplify the method.

机译：本发明涉及无机化学领域。通过化学传输反应使氯化铜-溴化五硫代磷酸五铜磷酸盐CuPS（BrI）的固溶体单晶生长的方法包括：将包含初始成分的真空石英安瓿以规定的化学计量比逐步加热至最高温度，并保持在相同温度在24小时内保持温度，并进一步生长单晶。基本：铜，磷，硫和硫;二元：溴化铜CuBr和碘化铜CuI用作合成的初始组分，最高合成温度为943±5 K，并使用化学计量比为的混合物进行生长。以20 mg / smof的小瓶游离体积的速率作为转运剂的CuBr / CuI。本发明的使用允许简化该方法。

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公开/公告号UA98263C2

专利类型
公开/公告日2012-04-25

原文格式PDF
申请/专利权人 UZHGOROD NATIONAL UNIVERSITY STATE HIGHER EDUCATIONAL INSTITUTION;
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申请/专利号UA20110004756
发明设计人 KOHAN OLEKSANDR PAVLOVYCH;PANKO VASYL VASYLIOVYCH;POHODIN ARTEM IHOROVYCH;PONOMARIOV VADYM YEVHENOVYCH;STUDENIAK IHOR PETROVYCH;
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申请日2011-04-18
分类号C30B11/14;
国家 UA
入库时间 2022-08-21 17:22:39

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