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CHIRAL ACYCLIC DIAMINOCARBENE LIGANDS, PRECURSORS THEREFORE AND THEIR USE IN ORGANIC SYNTHESIS REACTIONS
CHIRAL ACYCLIC DIAMINOCARBENE LIGANDS, PRECURSORS THEREFORE AND THEIR USE IN ORGANIC SYNTHESIS REACTIONS
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机译:手性环二氨基碳配体,其前体及其在有机合成反应中的用途
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摘要
The current application relates to a metal catalyst of formula (I): M[ADC][X]n, wherein M is a metal, ADC is a chiral acyclic diaminocarbene ligand, and X is a neutral or anionic ligand. The ADC ligand is prepared from the corresponding chiral formamidium salt precursor. The metal catalyst is used for asymmetric organic synthesis reactions such as hydrosilations, hydrogenations, conjugate additions, and cross-couplings.
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机译:本申请涉及式(I)的金属催化剂:M [ADC] [X] n Sub>,其中M是金属,ADC是手性无环二氨基卡宾配体,且X是中性或阴离子配体。 ADC配体由相应的手性甲form盐前体制备。该金属催化剂用于不对称有机合成反应,例如硅氢化,氢化,共轭加成和交叉偶联。
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