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Peroxide-based chemiluminescent assays and chemiluminescent compounds used therein

机译：基于过氧化物的化学发光测定法和其中使用的化学发光化合物

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摘要

A compound is provided having the formula:; embedded image

where C* is an sp²coordinated carbon atom; A is defined by the formula ; embedded image

wherein R₁₂, R₁₃, R₁₄, R₁₅, R₁₆, R₁₇, R₁₈and R₁₉are independently selected from the group consisting of hydrogen, alkyl, alkoxy, aryl, alkylaryl, heteroaryl, heteroalkoxy, aldehyde, keto, amino, nitro, halo, sulfate, sulfonyl, carboxy, carboxyester, phosphate or phosphoester, each of which may be substituted or unsubstituted; Z is a moiety that is covalently bonded to C* selected from the group consisting of O, S, N—R₁, and +N—R₁R₂where R₁and R₂are selected from hydrogen, alkyl, alkoxy, aryl, alkylaryl, heteroaryl, or heteroalkoxy moieties, each of which may be substituted or unsubstituted; and Q is a suitable leaving group yields a compound which is capable of exhibiting a chemiluminescent reaction in the presence of a peroxide or peroxide-like compound under aqueous or mixed aqueous-organic conditions.

机译：提供具有下式的化合物： “嵌入式图像”

其中C *是sp ^{2 配位碳原子; A是由公式定义的 ; 其中R _{12 ，R _{13 ，R _{14 ，R _{15 ，R _{16 ，R _{17 ，R _{18 和R _{19 分别选自氢，烷基，烷氧基，芳基，烷基芳基，杂芳基，杂烷氧基，醛，酮，氨基，硝基，卤代，硫酸根，磺酰基，羧基，羧基酯，磷酸酯或磷酸酯组成的组，它们各自可以被取代或未被取代; ListItem> Z是与C *共价键合的部分，C *选自O，S，NR _{1 和+ N-R _{1 R _{2 ，其中R _{1 和R _{2 选自氢，烷基，烷氧基，芳基，烷基芳基，杂芳基或杂烷氧基部分，它们各自可以被取代或未被取代;和 Q是合适的离去基团，该化合物能够在过氧化物或类似过氧化物的化合物存在下，在含水或混合的含水有机溶剂中显示化学发光反应条件。}}}}}}}}}}}}}}

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公开/公告号US7718576B2

专利类型
公开/公告日2010-05-18

原文格式PDF
申请/专利权人 ALEXANDER A. WALDROP III;CALVIN P. H. VARY;
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申请/专利号US20030457385
发明设计人 ALEXANDER A. WALDROP III;CALVIN P. H. VARY;
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申请日2003-06-10
分类号C40B30/00;
国家 US
入库时间 2022-08-21 18:51:11

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