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Intercalation compounds of graphite oxide With fluorine DERIVATIVES dodecahydro-closo-DODEKABORNOY acid and its salts and methods of making
Intercalation compounds of graphite oxide With fluorine DERIVATIVES dodecahydro-closo-DODEKABORNOY acid and its salts and methods of making
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机译：氧化石墨与氟的插层化合物十二氢-氯-十二烷基硼酸盐及其盐和制备方法
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FIELD: chemistry.;SUBSTANCE: invention can be used in making solid electrolytes. Intercalated compounds of graphite oxide with fluorine-substituted derivatives of dodecahydro-closo-dodecaboric acid and its salts with composition C4OxHy×nRzB12H12-mFm, where x=0.58-1.98, y=0.54-0.75, 0.4≤n≤1.98, z=2 for R - H+, NH4+, Li+, Na+, K+ or z=1 for R - Zn2+, Mg2+, Ca2+, Sr2+, Ba2+; m=2, 4 to 8, 10, 12 are obtained through combined concentration of aqueous gel of graphite oxide with fluorine-substituted derivatives of dodecahydro-closo-dodecaboric acid and its salts, taken in molar ratio 1:(0.4 to 1.98). The mixture is constantly stirred at temperature not above 40°C until formation of a solid product with subsequent drying over a dehydrating agent to constant weight.;EFFECT: obtaining compounds with high ion conduction.;3 cl, 2 tbl, 19 ex
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机译：领域：化学。物质：本发明可用于制备固体电解质。氧化石墨与十二碳氢-十二碳十二酸的氟取代衍生物及其盐的插入化合物，其组成为C 4 O x H y x nR z B 12 H 12-m F m ，其中x = 0.58-1.98，y = 0.54-对于R-H + ，NH 4 + ，Li + ，对于R-Zn 2 + ，Mg 2 + ，Na + ，K + 或z = 1 Ca 2 + ，Sr 2 + ，Ba 2 + ; m ＝ 2、4至8、10、12是通过将氧化石墨的水凝胶与十二氢-氯-十二碳十二酸及其盐的氟取代的衍生物进行合并浓缩而获得的，摩尔比为1：（0.4至1.98）。将混合物在不高于40°C的温度下持续搅拌，直到形成固体产物，然后在脱水剂上干燥至恒重。效果：获得具有高离子传导性的化合物; 3 cl，2 tbl，19 ex
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