首页> 外国专利> Electrochemical coating method for depositing a layer on a metallic work piece or a non-metallic workpiece with a metallic cover in a deposition bath, comprises providing two individual sequences within a deposition sequence

Electrochemical coating method for depositing a layer on a metallic work piece or a non-metallic workpiece with a metallic cover in a deposition bath, comprises providing two individual sequences within a deposition sequence

机译:用于在沉积浴中在具有金属盖的金属工件或非金属工件上沉积层的电化学涂覆方法,包括在沉积顺序中提供两个单独的顺序

摘要

The electrochemical coating method for depositing a layer on a metallic workpiece or a non-metallic workpiece with a metallic cover in a deposition bath comprising a deposition sequence (P) that is repeated once, comprises providing two individual sequences (A, B, C) within the deposition sequence, where the two individual sequences comprise different deposition processes within the deposition sequence. Each individual sequence comprises direct current, pure cathodic pulse, combination of cathodic and anodic pulses, and combination of cathodic and anodic pulses with up to 500 single pulses. The electrochemical coating method for depositing a layer on a metallic workpiece or a non-metallic workpiece with a metallic cover in a deposition bath comprising a deposition sequence (P) that is repeated once, comprises providing two individual sequences (A, B, C) within the deposition sequence, where the two individual sequences comprise different deposition processes within the deposition sequence. Each individual sequence comprises direct current, pure cathodic pulse, combination of cathodic and anodic pulses, combination of cathodic and anodic pulses with up to 500 single pulses, ramp- and/or triangle pulse, and each of the process in combination with a base current. Between two successive individual processes and/or after flow of the deposition sequence, an interruption of external current is carried out. The deposition process comprises a direct current deposition following of a pulsed deposition. The base current comprises 1-75% of deposition current density. The duration of the individual sequence is 1-3000 ms. The deposition bath consists of aqueous solution of salt, a salt melt and/or an ionic fluid. The deposition bath consists of solid materials for the installation into a deposited layer. The solid materials are particles, fibers, flakes and/or nanotubes. The coating comprises 2-12 layers, which are subjected with direct current, pure cathodic pulse, combination of cathodic and anodic pulses, combination of cathodic and anodic pulses with up to 500 single pulses, ramp- and/or triangle pulse, and each of the process in combination with a base current. The two layers are subjected with different processes. A second layer follows on a first primary layer subjected on the workpiece surface, where the second layer comprises an increased layer thickness than the primary layer. A third upper layer follows to the second layer, where the layer thickness of the upper layer is smaller than the second layer. The second layer is produced by a flow-less process. A thermal treatment is carried out between the applied layers. The layers are subjected by a plasma oxide process.
机译:在具有重复一次的沉积顺序(P)的沉积浴中,在具有金属盖的金属工件或具有金属盖的非金属工件上沉积层的电化学涂覆方法,包括提供两个单独的序列(A,B,C)在沉积序​​列中,其中两个单独的序列在沉积序列中包括不同的沉积过程。每个单独的序列包括直流电,纯阴极脉冲,阴极脉冲和阳极脉冲的组合以及阴极脉冲和阳极脉冲的组合(最多500个单脉冲)。在具有重复一次的沉积顺序(P)的沉积浴中,在具有金属盖的金属工件或具有金属盖的非金属工件上沉积层的电化学涂覆方法,包括提供两个单独的序列(A,B,C)在沉积序​​列中,其中两个单独的序列在沉积序列中包括不同的沉积过程。每个单独的序列包括直流电,纯阴极脉冲,阴极和阳极脉冲的组合,具有最多500个单脉冲的阴极和阳极脉冲的组合,斜坡和/或三角形脉冲,以及每个过程与基本电流的组合。在两个连续的独立过程之间和/或在沉积顺序进行之后,中断外部电流。沉积过程包括在脉冲沉积之后的直流沉积。基本电流占沉积电流密度的1-75%。各个序列的持续时间为1-3000毫秒。沉积浴由盐水溶液,盐熔体和/或离子流体组成。沉积浴由固体材料组成,用于安装到沉积层中。固体材料是颗粒,纤维,薄片和/或纳米管。该涂层包括2-12层,分别经受直流电,纯阴极脉冲,阴极和阳极脉冲的组合,具有最多500个单脉冲的阴极和阳极脉冲的组合,斜波和/或三角形脉冲,以及每个该过程结合基本电流。两层经受不同的过程。第二层紧接在工件表面上的第一主层上,其中第二层的厚度比主层的厚度大。第三上层跟随第二层,其中上层的层厚度小于第二层。第二层是通过无流工艺生产的。在所施加的层之间进行热处理。所述层通过等离子体氧化物工艺进行。

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