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POLYMER-METAL COMPOSITE PARTICLES, POLYMER-METAL NANOCOMPOSITES AND THE PRODUCTION METHOD THEREOF

机译:聚合物金属纳米颗粒,聚合物金属纳米复合材料及其制备方法

摘要

Polymer-metal composite particles, a polymer-metal nanocomposite having an excellent dispersed state of metal component by molding the polymer-metal composite particles, and manufacturing methods thereof are provided, wherein the polymer-metal composite particles are obtained by subjecting a metal component having weak chemical affinity with polymer to plasma treatment and bonding the plasma treated metal component onto surfaces of polymer particles, thereby modifying the surfaces of polymer particles with a high functional metal component. In a method for manufacturing polymer-metal composite particles(10) by coating a metal component(12) on surfaces of polymer particles(11), the method comprises: performing a polymerization process of a mixture of an initiator, deionized water, a monomer, and a cross-linking agent to synthesize polymer particles formed in a fine powder shape; subjecting a metal component to plasma treatment through plasma discharge to produce metal plasma particles; and colliding the produced metal plasma particles with surfaces of the fine powder-shaped polymer particles, thereby depositing the metal plasma particles onto the surfaces of the fine powder-shaped polymer particles to form polymer-metal composite particles having a core-shell structure in which the metal component is deposited onto the surfaces of the polymer particles, wherein the cross-linking agent is added to the mixture in an amount of 4 to 10% of the monomer weight. A preparation method of a polymer-metal nanocomposite(30) comprises molding the polymer-metal composite particles, prepared by the method for manufacturing polymer-metal composite particles, as a raw material to prepare a polymer-metal nanocomposite in which the metal component is distributed in a polymer matrix.
机译:提供了一种聚合物-金属复合颗粒,通过模塑该聚合物-金属复合颗粒而具有优异的金属组分分散状态的聚合物-金属纳米复合物及其制造方法,其中该聚合物-金属复合颗粒是通过对具有以下特征的金属组分进行处理而获得的:与聚合物对等离子体处理的化学亲和力弱,并将经等离子体处理的金属成分粘合到聚合物颗粒的表面,从而用高功能金属成分修饰聚合物颗粒的表面。在通过将金属组分(12)涂覆在聚合物颗粒(11)的表面上来制造聚合物-金属复合颗粒(10)的方法中,该方法包括:进行引发剂,去离子水,单体的混合物的聚合过程。 ;和交联剂,以合成以细粉状形成的聚合物颗粒;通过等离子体放电对金属成分进行等离子体处理以产生金属等离子体颗粒;使所产生的金属等离子体粒子与粉状聚合物细颗粒的表面碰撞,从而将金属等离子体颗粒沉积在粉状聚合物细颗粒的表面上以形成具有核-壳结构的聚合物-金属复合颗粒,其中将金属组分沉积在聚合物颗粒的表面上,其中将交联剂以单体重量的4%至10%的量添加到混合物中。聚合物-金属纳米复合材料的制备方法(30)包括将通过所述聚合物-金属复合颗粒的制造方法制备的聚合物-金属复合颗粒成型为原料,从而制备其中金属成分为金属的聚合物-金属纳米复合材料。分布在聚合物基质中。

著录项

  • 公开/公告号KR100811001B1

    专利类型

  • 公开/公告日2008-03-11

    原文格式PDF

  • 申请/专利权人 PLASMA ZENIX CORPORATION;

    申请/专利号KR20070099669

  • 发明设计人 PARK DONG HYUN;

    申请日2007-10-04

  • 分类号B22F1/02;C23C14;

  • 国家 KR

  • 入库时间 2022-08-21 19:52:26

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