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Method for the production of primary amines comprising a primary amino group which bound to an aliphatic or cycloaliphatic C-atom, and a cyclopropyl unit

机译:制备伯胺的方法,所述伯胺包含与脂族或脂环族C原子键合的伯氨基和环丙基单元

摘要

Process for preparing primary amines having a cyclopropyl unit and a primary amino group bound to an aliphatic or cycloaliphatic carbon atom (amine A) by cathodically reducing oximes having a cyclopropyl unit or oxime derivatives in which the hydrogen atom in the oxime group has been replaced by an alkyl or acyl group (oxime O) at a temperature of from 50 to 100° C. in an essentially anhydrous electrolyte solution in a divided electrolysis cell.
机译:通过阴极还原具有环丙基单元的肟或肟衍生物的方法,制备具有环丙基单元和与脂肪族或脂环族碳原子键合的伯氨基的伯胺的方法(胺A),其中肟基中的氢原子已被取代在分开的电解池中的基本上无水的电解质溶液中,在50至100℃的温度下,烷基或酰基(肟O)。

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