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Apparatus and Method for Optimizing the Efficiency of Germanium Junctions in Multi-Junction Solar Cells

机译:用于优化多结太阳能电池中锗结效率的装置和方法

摘要

Apparatus and Method for Optimizing the Efficiency of Germanium Junctions in Multi-Junction Solar Cells. In a preferred embodiment, an indium gallium phosphide (InGaP) nucleation layer is disposed between the germanium (Ge) substrate and the overlying dual-junction epilayers for controlling the diffusion depth of the n-doping in the germanium junction. Specifically, by acting as a diffusion barrier to arsenic (As) contained in the overlying epilayers and as a source of n-type dopant for forming the germanium junction, the nucleation layer enables the growth time and temperature in the epilayer device process to be minimized without compromising the integrity of the dual-junction epilayer structure. This in turn allows the arsenic diffusion into the germanium substrate to be optimally controlled by varying the thickness of the nucleation layer. An active germanium junction formed in accordance with the present invention has a typical diffused junction depth that is ⅕ to ½ of that achievable in prior art devices. Furthermore, triple-junction solar cells incorporating a shallow n-p germanium junction of the present invention can attain 1 sun AMO efficiencies in excess of 26%.
机译:用于优化多结太阳能电池中锗结效率的装置和方法。在优选实施例中,磷化铟镓(InGaP)成核层设置在锗(Ge)衬底和上面的双结外延层之间,以控制n掺杂在锗结中的扩散深度。具体地,通过充当对上覆外延层中所含砷的扩散阻挡层以及作为形成锗结的n型掺杂剂的来源,成核层可以使外延层器件工艺中的生长时间和温度最小化而不会损害双结外延层结构的完整性。这进而允许通过改变成核层的厚度来最佳地控制砷扩散到锗衬底中。根据本发明形成的有源锗结具有典型的扩散结深度,其为现有技术装置中可达到的典型的扩散结深度的1/3至1/2。此外,结合了本发明的浅n-p锗结的三结太阳能电池可以获得超过26%的1个太阳AMO效率。

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