首页> 外国专利> Exchanging reactor to carry out steam reforming reactions, comprises an enclosure, a distribution unit to distribute a charge through a fixed-bed catalytic zone, and a collection unit to collect an effluent from the catalytic zone

Exchanging reactor to carry out steam reforming reactions, comprises an enclosure, a distribution unit to distribute a charge through a fixed-bed catalytic zone, and a collection unit to collect an effluent from the catalytic zone

机译:用于进行蒸汽重整反应的交换反应器,包括:外壳;分配单元,其通过固定床催化区分配电荷;以及收集单元,其用于收集来自催化区的流出物。

摘要

The exchanging reactor (1) to carry out steam reforming reactions, comprises an enclosure (2), a distribution unit to distribute a charge through a fixed-bed catalytic zone (10), a collection unit to collect an effluent from the catalytic zone, and a heating unit of the catalytic zone. The collection unit comprises pipes crossing through the catalytic zone. The heating unit of the catalytic zone comprises a combustion zone (13) placed near the catalytic zone, and a supply unit of the combustion zone having oxidizing and fuel gas mixture. The exchanging reactor (1) to carry out steam reforming reactions, comprises an enclosure (2), a distribution unit to distribute a charge through a fixed-bed catalytic zone (10), a collection unit to collect an effluent from the catalytic zone, and a heating unit of the catalytic zone. The collection unit comprises pipes crossing through the catalytic zone. The heating unit of the catalytic zone comprises a combustion zone (13) placed near the catalytic zone, a supply unit of the combustion zone having oxidizing and fuel gas mixture, an evacuation unit of an effluent gas resulting from combustion, and a recirculation tube of the gas effluent. The distribution unit comprises a perforated lower tubular plate (4) in which perforations are prolonged by tubular elements called charge tubes. The catalytic zone comprises a lower inert zone placed on the lower tubular plate in which the inert zone has a thickness corresponding to a length of the charge tubes. The pipes are useful to collect the effluents resulting from the catalytic zone, and are arranged between a collection chamber, which is placed downstream from the catalytic zone and the evacuation units of the effluents. The pipes cross the lower tubular plate in an internal space of the charge tubes in which the pipes are distributed in the catalytic zone and inserted between the heating unit. The heating unit is contained in sheaths, which are partly immersed in the catalytic zone. The sheats are opened in one end and closed in other end. The open end of the sheath is fixed at an upper tubular plate, which is delimiting the collection chamber situated at the top of the catalytic zone. The pipes and sheaths comprise wings on an external wall of the pipes to increase contact surface of the catalytic zone. The heating unit is constituted by the coaxial parts having a supply tube in oxidizing gas mixture, which is emerging in the sheath at the upper level of the catalytic zone and at a bottom of the sheaths, a fuel distribution unit called fuel tube connected to one end of a fuel supply unit and placed inside the supply tube of oxidizing gas mixture, and an oxidation catalyst disposed inside and on a portion of the supply tube of oxidizing gas mixture and downstream of the fuel distribution tube. The recirculation tube is placed in the sheath downstream of the combustion zone. The fuel supply unit is placed inside the supply tube of oxidizing gas mixture, and is prolonged until the bottom of the sheaths. The fuel tube comprises a portion of porous wall. The supply tube of oxidizing gas mixture is filled all along its height and upto the upper end of the catalytic zone of the oxidation catalyst. A coolant is injected into the collection chamber of the effluent resulting from catalytic zone. A perforated upper tubular plate is made up of double wall to allow the circulation of a coolant in the internal space of the charge tubes. An independent claim is included for a method to carry out an endothermic reaction in a fixed-bed catalytic zone.
机译:进行蒸汽重整反应的交换反应器(1)包括外壳(2),分配单元以通过固定床催化区(10)分配电荷,收集单元以收集来自催化区的废水,催化区的加热单元。收集单元包括穿过催化区的管道。催化区的加热单元包括位于催化区附近的燃烧区(13)和具有氧化和燃料气体混合物的燃烧区的供应单元。进行蒸汽重整反应的交换反应器(1)包括外壳(2),分配单元以通过固定床催化区(10)分配电荷,收集单元以收集来自催化区的废水,催化区的加热单元。收集单元包括穿过催化区的管道。催化区的加热单元包括位于催化区附近的燃烧区(13),具有氧化和燃料气体混合物的燃烧区的供应单元,燃烧产生的废气排放单元以及燃烧室的再循环管。废气。分配单元包括带孔的下部管状板(4),在该下部板中,孔被称为充气管的管状元件延长。催化区包括位于下部管状板上的下部惰性区,其中惰性区的厚度对应于装料管的长度。这些管可用于收集由催化区产生的流出物,并布置在收集室和流出装置之间,该收集室位于催化区的下游。这些管在充电管的内部空间中穿过下部管状板,在该内部空间中,这些管分布在催化区域中并插入加热单元之间。加热单元装在护套中,护套部分浸入催化区。护套的一端打开,另一端封闭。护套的开口端固定在上部管状板上,该上部管状板界定了位于催化区顶部的收集室的边界。管和护套在管的外壁上包括翼以增加催化区的接触表面。加热单元由同轴部分构成,该同轴部分具有在氧化剂区域内的鞘层中以及在鞘层底部处出现在氧化气体混合物中的氧化性气体供应管,与一个燃料分配单元相连的燃料分配单元燃料供应单元的一端并放置在氧化剂气体混合物的供应管内部,氧化催化剂布置在氧化剂气体混合物的供应管的内部和一部分上并且在燃料分配管的下游。再循环管放置在燃烧区下游的护套中。燃料供应单元放置在氧化性气体混合物的供应管内,并延长至护套底部。燃料管包括多孔壁的一部分。氧化气体混合物的供应管一直沿其高度充满,直到氧化催化剂的催化区的上端。冷却剂被注入催化区产生的废水收集室。多孔的上部管状板由双壁制成,以允许冷却液在充气管的内部空间中循环。包括在固定床催化区中进行吸热反应的方法的独立权利要求。

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