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Catalyst zeolite, support a base of the matrix silico - aluminium and of zeolite, and advantages of hydrocracking of charges hydrocarbon

机译:催化剂沸石,支撑基质硅铝和沸石的基料,以及烃类加氢裂化的优势

摘要

New catalyst comprises a Group VIB and/or VIII metal hydrogenation-dehydrogenation component on a support comprising a zeolite and a silica-alumina matrix with a silica content of 5-95 wt.%, where the catalyst has defined physicochemical characteristics. New catalyst comprises a Group VIB and/or VIII metal hydrogenation-dehydrogenation component on a support comprising a zeolite and a silica-alumina matrix with a silica content of 5-95 wt.%. The catalyst has an average pore diameter measured by mercury porosimetry of 20-140 Angstroms, a total pore volume measured by mercury porosimetry of 0.1-0.6 ml/g, a total pore volume measured by nitrogen porosimetry of 0.1-0.6 ml/g, a BET specific surface of 100-600 m 2/g, pore volumes in pores of diameter above 140, above 160, above 200 and above 500 Angstroms of less than 0.1, 0.1, 0.1 and 0.01 ml/g respectively (all measured by mercury porosimetry), a tamped bulk density above 0.85 g/cm 3, and an x-ray diffraction pattern with at least principal lines characteristic of alpha, rho, chi, eta, gamma, kappa, theta or delta alumina. Independent claims are also included for: (1) catalyst support as above; (2) hydrocracking and/or hydroconversion of hydrocarbon feeds using a catalyst as above or a catalyst comprising a support as above; (3) hydrotreating of hydrocarbon feeds using a catalyst as above or a catalyst comprising a support as above.
机译:新的催化剂在载体上包含VIB和/或VIII族金属氢化-脱氢组分,该载体包含沸石和二氧化硅含量为5-95wt。%的二氧化硅-氧化铝基质,其中该催化剂具有确定的理化特性。新催化剂在载体上包含VIB和/或VIII族金属加氢-脱氢组分,该载体包含沸石和二氧化硅含量为5-95重量%的二氧化硅-氧化铝基质。该催化剂具有通过水银孔隙率法测得的平均孔径为20-140埃,通过水银孔隙率法测得的总孔径为0.1-0.6ml / g,通过氮气孔隙率法测得的总孔径为0.1-0.6ml / g, BET比表面积为100-600 m 2> / g,直径在140埃以上,160埃以上,200埃以上和500埃以上的孔中的孔体积分别小于0.1、0.1、0.1和0.01 ml / g(均通过汞测量)孔隙率法),高于0.85 g / cm 3的夯实堆积密度和至少具有α,rho,chi,eta,γ,κ,θ或δ氧化铝特征的主线的X射线衍射图。还包括以下方面的独立权利要求:(1)如上所述的催化剂载体; (2)使用上述催化剂或包含上述载体的催化剂对烃类进料进行加氢裂化和/或加氢转化; (3)使用上述催化剂或包含载体的催化剂对烃进料进行加氢处理。

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