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METHOD OF FORMING MIXED RARE EARTH OXIDE AND MIXED RARE EARTH ALUMINATE FILMS BY ATOMIC LAYER DEPOSITION

机译:原子层沉积形成稀土氧化物和稀土铝酸盐混合膜的方法

摘要

A method is provided for depositing a gate dielectric that includes at least two rare earth metal elements in the form of an oxide or an aluminate. The method includes disposing a substrate (25, 92) in a process chamber (10) and exposing the substrate (25, 92) to a gas pulse containing a first rare earth precursor and to a gas pulse containing a second rare earth precursor. The substrate (25, 92) may also optionally be exposed to a gas pulse containing an aluminum precursor. Sequentially after each precursor gas pulse, the substrate (25, 92) is exposed to a gas pulse of an oxygen-containing gas. In alternative embodiments, the first and second rare earth precursors may be pulsed together, and either or both may be pulsed together with the aluminum precursor. The first and second rare earth precursors comprise a different rare earth metal element. The sequential exposing steps may be repeated to deposit a mixed rare earth oxide or aluminate layer (96) with a desired thickness. Purge or evacuation steps may also be performed after each gas pulse.
机译:提供一种用于沉积包括至少两种氧化物或铝酸盐形式的稀土金属元素的栅极电介质的方法。该方法包括将基板(25、92)布置在处理室(10)中,并将基板(25、92)暴露于包含第一稀土前体的气体脉冲和包含第二稀土前体的气体脉冲。衬底(25、92)也可以可选地暴露于包含铝前体的气体脉冲。在每个前体气体脉冲之后,依次将基板(25、92)暴露于含氧气体的气体脉冲中。在替代实施例中,可以将第一稀土前体和第二稀土前体脉冲在一起,并且可以将其中之一或两者与铝前体脉冲在一起。第一和第二稀土前体包括不同的稀土金属元素。可以重复顺序的曝光步骤,以沉积具有期望厚度的混合稀土氧化物或铝酸盐层(96)。在每个气体脉冲之后也可以执行吹扫或抽空步骤。

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