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METHOD FOR PREPARING HOLLOW NANOFIBER, HOLLOW NANOFIBER AND CATALYST COMPOSITION FOR PREPARING HOLLOW NANOFIBER

机译:空心纳米纤维的制备方法,空心纳米纤维和制备空心纳米纤维的催化剂组合物

摘要

A method for preparing hollow nanofibers having carbon as a primary component, which comprises contacting a carbon-containing compound with a catalyst at a temperature of 500 to 1200 DEG C, wherein as the catalyst use is made of a catalyst comprising a zeolite exhibiting the thermal resistance at 900 DEG C and, supported thereon, a metal; a catalyst comprising a metallosilicate zeolite containing a heteroatom except aluminum and silicon in the structural framework thereof and, supported thereon, a metal; a catalyst comprising a supporting material and, supported thereon, fine cobalt particles exhibiting a binding energy of a cobalt 2P3/2 electron of 779.3 to 781.0 eV, as measured by the X-ray photoelectron spectroscopy; a catalyst comprising a supporting material and, supported thereon, fine cobalt particles exhibiting a cobalt atom ratio in the surface of the supporting material of 0.1 to 1.5%, as measured by the X-ray photoelectron spectroscopy under a condition of 10 kV and 18 mA; a catalyst comprising a supporting material and, supported thereon, fine cobalt particles exhibiting a weight ratio of cobalt to a second metal component (weight of cobalt/weight of the second metal component) of 2.5 or more; or a catalyst comprising a zeolite having a film form and, supported on the surface thereof, a metal.
机译:一种制备以碳为主要成分的中空纳米纤维的方法,该方法包括使含碳化合物与催化剂在500至1200℃的温度下接触,其中作为催化剂,使用包含表现出热的沸石的催化剂。在900℃的电阻和在其上支撑的金属;催化剂,其包含金属硅酸盐沸石,该金属硅酸盐沸石在其结构框架中含有除铝和硅以外的杂原子,并在其上负载有金属。用X射线光电子能谱法测定的催化剂,该催化剂包含载体材料和负载在其上的细钴颗粒,该细钴颗粒表现出779.3至781.0eV的钴2P3 / 2电子的结合能。催化剂,该催化剂包含载体材料,并在其上负载了在10 kV和18 mA的条件下通过X射线光电子能谱测得的,在载体材料表面表现出0.1%至1.5%的钴原子比的细钴颗粒。 ;催化剂,其包含载体材料和在其上负载的钴与第二金属成分的重量比(钴的重量/第二金属成分的重量)为2.5以上的钴微粒。或包含具有膜形式的沸石的催化剂,该沸石负载在其表面上是金属。

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