首页> 外国专利> PROCESS FOR PREPARING A COPOLYMER OF THE ACRYLAMIDE-SODIUM ACRYLATE-TYPE TO MODIFY THE FIELD PERMEABILITY PROFILE OF FORMATION WATER AT HIGH TEMPERATURES AND SALINITIES

PROCESS FOR PREPARING A COPOLYMER OF THE ACRYLAMIDE-SODIUM ACRYLATE-TYPE TO MODIFY THE FIELD PERMEABILITY PROFILE OF FORMATION WATER AT HIGH TEMPERATURES AND SALINITIES

机译:制备丙烯酰胺-丙烯酸钠型共聚物以修饰高温高压下地层水的渗透系数的方法

摘要

The invention relates to a process for preparing a polymer whose molecular mass and anionicity degree are especially established for temperatures of up to 110A C and a ionic content of formation water ranging from a very low to a very high level (TDS=0.06...30 g%), to be used in gelation systems to modify the permeability profile of oil fields. The synthesis of the acrylic polymer is based on the copolymerization rection between acrylamide and sodium acrylate, in an aqueous solution, at a concentration of 6...10% For adjusting the molecular mass, a disodic salt of the ethylenediaminotetra-acetic acid is admixed. As initiating agents there is employed the potassium persulphate/sodium sulphite redox system or thermolabile organic initiating agents. With a view to increasing the resistance to temperatures of up to 110A C and salinities of up to 30 g%, potassium iodide is admixed. The R-type copolymer is presented as an aqueous solution having 7...10% active substance, a molecular mass of 0.8...2.2x10^6 g/mole, KH=0.5...0.55, an anionicity degree of 6...12% and pH=5.5...7.
机译:本发明涉及一种制备聚合物的方法,该聚合物的分子量和阴离子度特别是在高达110℃的温度和地层水的离子含量从非常低到非常高的水平(TDS = 0.06 ... 30 g%),用于凝胶化系统,以改变油田的渗透率曲线。丙烯酸类聚合物的合成基于丙烯酰胺和丙烯酸钠在水溶液中的共聚反应,浓度为6 ... 10%。为了调节分子量,将乙二氨基四乙酸的二碘盐混合。作为引发剂,使用过硫酸钾/亚硫酸钠氧化还原系统或热不稳定的有机引发剂。为了提高对高达110A C的温度的耐受性和高达30 g%的盐度,混入了碘化钾。 R型共聚物以具有7 ... 10%活性物质,分子量为0.8 ... 2.2x10 ^ 6 g / mol,KH = 0.5 ... 0.55,阴离子度为6的水溶液形式存在... 12%且pH = 5.5 ... 7。

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