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A process for producing an aromatic dibasic acid using a single catalyst system

机译:使用单一催化剂体系生产芳族二元酸的方法

摘要

Disclosed is a process for manufacturing an aromatic diacid in one step with a single catalyst system which comprises: a) introducing into a reactor an aromatic hydrocarbon containing the number of rings desired in the product diacid with one or more alkyl groups attached to the rings; b) reacting said aromatic hydrocarbon in the presence of an oxidant supply and a single catalyst system comprising at least one catalyst selected from Group IB, IIB, VB, or VIIB of the Periodic Table, in a reaction medium capable of stabilizing the aromatic acids formed against further oxidation to water and CO2, or decarboxylation to aromatic hydrocarbons, and also capable of allowing the isomerization of the acids so formed to the desired diacids; and c) reacting said hydrocarbon feed with said oxidant in the presence of said catalyst system until a desired amount of said feed is oxidized to carboxylic acids and isomerized to the desired diacid product.
机译:公开了一种用单一催化剂体系一步制备芳族二酸的方法,该方法包括:a)将包含产物二酸中所需数目的环的芳族烃引入反应器中,所述产物二酸中具有一个或多个连接在环上的烷基; b)在能够稳定所形成的芳族酸的反应介质中,使所述芳族烃在氧化剂供应和包含至少一种选自周期表的IB,IIB,VB或VIIB族的催化剂的单一催化剂体系的存在下反应防止进一步氧化为水和二氧化碳,或脱羧为芳烃,并且还能够将如此形成的酸异构化为所需的二酸; c)在所述催化剂体系的存在下,使所述烃进料与所述氧化剂反应,直到所需量的所述进料被氧化成羧酸并异构化为所需的二酸产物。

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