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Corrosion inhibiting MIXTURE AND MATERIALS coatings containing corrosion inhibiting MIXTURE

机译:含缓蚀混合物的缓蚀混合物和材料涂料

摘要

1. The corrosion inhibiting mixture comprising (A1) corrosion inhibiting pigments (A2) amorphous silica modified with metal ions, and (A3) at least one compound of general formula IRO-M [-OP (O) (OH) -OP (O ) (OR1) 2] 3 · HP (O) (OR2) 2, where the variables and indices have the following meanings: M is selected from the group of Lewis acceptors, R, R1 represent, independently of each other aliphatic and cycloaliphatic ostatki.2 R2. A corrosion inhibiting blend of claim 1 wherein the corrosion inhibiting pigments (A1) is selected from the group consisting of zinc phosphate, zinc metaborate and bariya.3 metaborate monohydrate. Corrosion inhibiting mixture according to claim 2, characterized in that the metal ions in the compound (A2) is selected from the group consisting of alkali metal ions, alkaline earth metal, scandium, yttrium, lanthanum and lanthanides, as well as zinc ions and alyuminiya.4. A corrosion inhibiting blend of claim 3, wherein the metal ions are ions kaltsiya.5. Corrosion inhibiting mixture of claim 4, wherein the central atom M in the compound (A3) is selected from the group consisting of aluminum, titanium and tsirkoniya.6. Corrosion inhibiting mixture according to claim 5, characterized in that M = titan.7. A corrosion inhibiting blend of claim 6, characterized in that the components (A1), (A2) and (A3) are in a weight ratio of 1: (0.5-1.5) :( 0.1-2). 8. A corrosion inhibiting blend of claim 7, characterized in that it comprises at least one electrically conductive pigment (A4) .9. A corrosion inhibiting blend of claim 8, wherein said electrically conductive pigment (A4) has at least a bimodal particle distribution razmeram.10. A corrosion inhibiting blend of claim 9, characterized in that the electrically conductive pigment (A4) is selected from the group consisting of elemental silicon and water-insoluble phosphides metallov.11. Coating materials containing corrosion inhibiting mixture comprising (A1) corrosion inhibiting pigments, (A2) amorphous silica modified with metal ions, and (A3) at least one compound of general formula IMn (X) m, (I), where the variables and indices have the following meanings: M at least one central atom selected from the group of acceptors Lewis X ligands donor Lewis least one bridging atom selected from elements of the 5th and 6th main group of the periodic system of elements, n of 1 to 500 and m 3 to 2,000.12. Coating materials according to claim 11, characterized in that the corrosion inhibiting pigment (A1) is selected from the group consisting of zinc phosphate, zinc metaborate and bariya.13 metaborate monohydrate. Coating materials according to claim 11, characterized in that the metal ions in the compound (A2) is selected from the group consisting of alkali metal ions, alkaline earth metal, scandium, yttrium, lanthanum and lanthanides, as well as zinc ions and alyuminiya.14. Coating materials according to claim 11, characterized in that the central atom M in the compound (A3) is selected from the group consisting of aluminum, titanium and tsirkoniya.15. Coating materials according to claim 11, characterized in that the bridging atom X in the compound (A3) is selected from the group consisting of nitrogen, phosphorus, oxygen and sery.16. Coating materials according to claim 11, characterized in that the components (A1), (A2) and (A3) are in a weight ratio of 1: (0.5-1.5) :( 0.1-2) .17 . Coating materials according to claim 11, characterized in that they contain the component (A1) in an amount of 0.1-10 wt.%, Based on the solid phase material corresponding pokrytiya.18. Coating materials according to claim 17, characterized in that they comprise component (A2) in an amount of 0.1-10 wt.%, Based on the solid phase material corresponding pokrytiya.19. Coating materials according to claim 18, characterized in that they comprise component (A3) in an amount of 0.01-5 wt.%, Based on the solid phase material corresponding pokrytiya.20. Coating materials according to claim 19, characterized in that they comprise at least an electrically conductive pigment (A4) in an amount of 10-80 wt.%, Based on the solid phase material corresponding pokrytiya.21. Coating materials according to claim 20, characterized in that the weight ratio of the components (A1), (A2) and (A3), on the one hand, to the electrically conductive pigment (A4), on the other hand, is from 1:20 to 1: 5.22 . Coating materials according to claim 21, characterized in that they are single-component sistemami.23. Coating materials according to claim 22, characterized in that they are thermally, with actinic radiation, or thermally and with actinic radiation otverzhdaemymi.24. Coating materials according to claim 23, characterized in that they are conventional or aqueous coating materials, substantially or wholly anhydrous or free of organic solvent, the liquid coating material (a 100% system), or substantially or completely non-aqueous or organic solvent free from solid , powdery coating materials (powder coatings), or anhydrous dispersions of powder coatings (coatings suspension) .25. The coating materials according to claim 24, characterized in that they are a lacquer coating for rolls.
机译:1.一种缓蚀混合物,其包含(A1)缓蚀颜料(A2)用金属离子改性的无定形二氧化硅,和(A3)至少一种通式为IRO-M [-OP(O)(OH)-OP(O)的化合物)(OR1)2] 3·HP(O)(OR2)2,其中变量和索引具有以下含义:M选自路易斯受体,R,R1彼此独立地表示脂肪族和脂环族的ostatki .2 R2。权利要求1的腐蚀抑制混合物,其中腐蚀抑制颜料(A1)选自磷酸锌,偏硼酸锌和三价偏硼酸钡。 3.根据权利要求2的缓蚀混合物,其特征在于化合物(A2)中的金属离子选自碱金属离子,碱土金属,scan,钇,镧和镧系元素,以及锌离子和铝.4。 4.根据权利要求3所述的腐蚀抑制混合物,其中,所述金属离子是离子钾。5。 5.权利要求4的腐蚀抑制混合物,其中化合物(A3)中的中心原子M选自铝,钛和tsirkoniya。6。 6.根据权利要求5的缓蚀混合物,其特征在于,M = titan.7。 7.根据权利要求6所述的腐蚀抑制混合物,其特征在于,所述组分(A1),(A2)和(A3)的重量比为1:(0.5-1.5):( 0.1-2)。 8.根据权利要求7所述的腐蚀抑制混合物,其特征在于,它包括至少一种导电颜料(A4).9。 9.根据权利要求8所述的腐蚀抑制混合物,其中,所述导电颜料(A4)具有至少双峰颗粒分布的razmeram.10。 11.根据权利要求9所述的腐蚀抑制混合物,其特征在于,所述导电颜料(A4)选自元素硅和水不溶性磷化物金属11。包含缓蚀混合物的涂料,包含(A1)缓蚀颜料,(A2)经金属离子改性的无定形二氧化硅和(A3)至少一种通式为IMn(X)m,(I)的化合物,其中变量和指数具有以下含义:M至少一个选自受体路易斯X配体供体的中心原子路易斯至少一个选自元素周期系统的第5和第6主族元素的桥原子,n为1至500和m 3至2,000.12。 12.根据权利要求11所述的涂料,其特征在于,所述腐蚀抑制颜料(A1)选自磷酸锌,偏硼酸锌和偏亚硝酸钡一水合物。 12,根据权利要求11的涂料,其特征在于化合物(A2)中的金属离子选自碱金属离子,碱土金属,scan,钇,镧和镧系元素,以及锌离子和铝。 14。 12.根据权利要求11所述的涂料,其特征在于,化合物(A3)中的中心原子M选自铝,钛和tsirkoniya 15。 12,根据权利要求11的涂料,其特征在于化合物(A3)中的桥连原子X选自氮,磷,氧和二十六。 12.根据权利要求11所述的涂料,其特征在于,所述组分(A1),(A2)和(A3)的重量比为1:(0.5-1.5):( 0.1-2).17。 12.根据权利要求11所述的涂料,其特征在于,基于固相材料,它们包含0.1-10重量%的组分(A1)相应的pokrytiya.18。 18.根据权利要求17所述的涂料,其特征在于,基于固相材料,它们包含含量为0.1-10重量%的组分(A2)相应的pokrytiya.19。 19.根据权利要求18的涂料,其特征在于,基于固相材料,它们包含的组分(A3)的量为0.01-5重量%,相应的pokrytiya.20。 20.根据权利要求19所述的涂料,其特征在于,基于固相材料,至少包含10-80重量%的导电颜料(A4),对应于pokrytiya.21。 21.根据权利要求20的涂料,其特征在于,组分(A1),(A2)和(A3)一方面与导电颜料(A4)的重量比为1。 :20至1:5.22。 22.根据权利要求21的涂料,其特征在于它们是单组分sistemami.23。 24.根据权利要求22所述的涂料,其特征在于,它们是热的,光化辐射的,或者是热的且光化辐射的otverzhdaemymi.24。 24.根据权利要求23的涂料,其特征在于它们是常规或水性涂料,基本上或完全无水或不含有机溶剂,液体涂料(100%体系),或基本上或完全不含水或有机溶剂从固体,粉末涂料(粉末涂料)或粉末涂料的无水分散体(涂料悬浮液).25。 25.根据权利要求24所述的涂料,其特征在于,它们是用于辊的漆涂层。

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