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SUPPRESSOR FOR CONTINUOUS ELECTROCHEMICALLY SUPPRESSION ION CHROMATOGRAPHY AND METHOD

机译:连续电化学抑制离子色谱的抑制剂和方法

摘要

Methods and devices for continuous electrochemically suppressed ion chromatography are disclosed. In preferred aspect of the invention, a chromatography effluent comprising analyte ions and electrolyte is split into a first chromatography effluent flow stream and a second chromatography effluent flow stream. Electrolysis ions selected from the group consisting of hydronium ions and hydroxide ions are generated by the electrolysis of water. Electrolysis ions of the same charge as the electrolyte and the second chromatography effluent stream are flowed through a stationary phase thereby suppressing the electrolyte in the second chromatography effluent flow stream. The analyte ions are subsequently detected in the suppressed second chromatography effluent flow stream.
机译:公开了用于连续电化学抑制的离子色谱的方法和装置。在本发明的优选方面,将包含分析物离子和电解质的色谱流出物分成第一色谱流出物流和第二色谱流出物流。通过水的电解产生选自水合氢离子和氢氧根离子的电解离子。与电解质和第二色谱流出物流相同电荷的电解离子流过固定相,从而抑制第二色谱流出物中的电解质。随后在抑制的第二色谱流出液中检测到分析物离子。

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