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A method of purifying water solutions obtained from ion exchanger regeneration and device for purifying water solutions obtained from ion exchanger regeneration.

机译:一种纯化从离子交换剂再生获得的水溶液的方法和一种纯化从离子交换剂再生获得的水溶液的装置。

摘要

1. The method of purifying water solutions obtained from ion exchanger regeneration consists in their separation by the method of membrane distillation into pure water and the concentrate. It is characterised in that the post-regeneration solution in a non-saturated state is heated up to the temperature, that does not exceed 333 K. The flow intensities along membrane surfaces are adjusted to ensure the temperature of the solution leaving the module is not lower than 326 K, while the temperature of water flowing on the other membrane side at the module inlet is at least 293 K. During the flow through the membrane module, the post-regeneration solution is condensed through the evaporation of water through the pores of the non-moistened hydrophobic membrane. Then, the evaporating water is condensed and collected on the other membrane side, while the condensed solution is crystallised at the temperature under 320 K. Then, the nuclei of crystallisation are removed from the solution and new portions of purified solution are added in the amount, which compensates the volume of the precipitated salt and the volume of evaporated water. Then, the solution undergoes concentration again. 3. The device for purifying water solutions obtained from ion exchanger regeneration by membrane distillation combined with salt crystallisation. It is characterised in that it has an additional circulation tank (4). The precipitate funnel of the latter is connected to the crystallizer (7). The outlet of the latter is connected to the precipitate funnel of the circulation tank (4). The top outlet of the tank (4) is connected to the outlet of the storage reservoir of post-regeneration solutions (1). The latter is connected through the heat exchanger (2) to the inlet of the feed into the section of membrane modules (3). The other inlet of the membrane section (3) is connected through the heat exchanger (6) to the condensate tank (5), connected to the outlet of the distillate circulation in the membrane section (3).
机译:1.纯化从离子交换剂再生获得的水溶液的方法包括通过膜蒸馏的方法将其分离成纯水和浓缩物。其特征在于,将处于非饱和状态的再生后溶液加热到不超过333 K的温度。调节沿膜表面的流动强度,以确保离开模块的溶液温度不会升高。低于326 K,而在组件入口处在另一膜侧流动的水的温度至少为293K。在流经膜组件的过程中,再生后的溶液通过水通过细孔的蒸发而冷凝未润湿的疏水膜。然后,将蒸发的水冷凝并收集到膜的另一侧,同时将冷凝的溶液在320 K的温度下结晶。然后,从溶液中除去结晶核,并添加适量的新部分纯化溶液。 ,它补偿了沉淀盐的体积和蒸发水的体积。然后,溶液再次浓缩。 3.用于纯化通过膜蒸馏结合盐结晶从离子交换剂再生中获得的水溶液的装置。其特征在于,它具有附加的循环罐(4)。后者的沉淀漏斗连接到结晶器(7)。后者的出口连接到循环罐(4)的沉淀漏斗。储罐(4)的顶部出口连接至再生后溶液(1)的储存槽的出口。后者通过热交换器(2)连接到进料到膜组件(3)部分的入口。膜部分(3)的另一个入口通过热交换器(6)连接到冷凝水箱(5),冷凝水箱(5)连接到膜部分(3)中的馏出物循环的出口。

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