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Energy-transfer type light-emitting polymer based on poly(p-phenylene vinylene) and preparation thereof

机译:基于聚对亚苯基亚乙烯基的能量转移型发光聚合物及其制备

摘要

This invention relates to an energy-transfer type light-emitting polymers based on poly(p-phenylene vinylene)s containing two or more kinds of luminous elements which are completely isolated by an ether group in the backbone, having the following structural formula. The conjugated length of each kind of luminous element can be adjusted and different luminous elements can be effectively isolated by an ether bond as a linking element and an isolating element. Meanwhile, different luminous elements can independently emit, which provides the precondition of energy transfer between different luminous elements in relation to molecular structure and therefore the fluorescence quantum efficiency can be improved. chemistry chemdraw filechemistry mol file;wherein Ar1, Ar2, R1, R2, R3, R4, x and y are defined as in claims.
机译:本发明涉及基于聚(对亚苯基亚乙烯基)的能量传递型发光聚合物,其具有以下结构式,所​​述发光体在主链中被醚基完全隔离而包含两种以上的发光元素。可以调节每种发光元件的共轭长度,并且可以通过醚键作为连接元件和隔离元件来有效地隔离不同的发光元件。同时,不同的发光元件可以独立发光,这为分子结构之间不同的发光元件之间的能量转移提供了前提,因此可以提高荧光量子效率。 <图像文件=“ US20040234811A1-20041125-C00001.GIF” he =“ 117.369” id =“ EMI-C00001” imgContent =“ undefined” imgFormat =“ GIF” wi =“ 212.9085“ /> 化学化学绘图文件 化学摩尔文件 ;其中Ar 1 ,Ar 2 ,R 1 ,R 2 ,R 3 ,R 4 ,x和y如权利要求中所定义。

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