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Photovoltaic devices fabricated from insulating nanostructured template
Photovoltaic devices fabricated from insulating nanostructured template
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机译:由绝缘纳米结构模板制成的光伏器件
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摘要
Photovoltaic devices, such as solar cells, and methods for their manufacture are disclosed. A device may be characterized by an architecture with an inorganic insulating nanostructured template having template elements between about 1 nm and about 500 nm in diameter with a elements density of between about 1012 elements/m2 and about 1016 elements/m2. A first charge-transfer material coats the walls of the template elements leaving behind additional space. A second charge-transfer material fills the additional space such that the first and second charge-transfer materials are volumetrically interdigitated. At least one charge transfer material has an absorbance of greater than about 103/cm. The first and second charge-transfer materials have complementary charge transfer properties with respect to each other. A lowest unoccupied molecular orbital (LUMO) or conduction band of the first charge-transfer material is offset from a LUMO or conduction band of the second charge-transfer material by greater than about 0.2 eV. An electrically conductive material may optionally be disposed between the nanostructured template and the first charge-transfer material.
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机译:公开了诸如太阳能电池之类的光伏装置及其制造方法。装置的特征可以在于具有无机绝缘纳米结构模板的体系结构,该模板具有直径在约1nm至约500nm之间的模板元素,且元素密度在约10 12 Sup> elements / m 2之间 Sup>和大约10 16 Sup>个元素/ m 2 Sup>。第一电荷转移材料覆盖模板元件的壁,留下额外的空间。第二电荷转移材料填充额外的空间,使得第一和第二电荷转移材料在体积上相互交叉。至少一种电荷转移材料的吸光度大于约10 3 Sup> / cm。第一和第二电荷转移材料相对于彼此具有互补的电荷转移特性。第一电荷转移材料的最低未占据分子轨道(LUMO)或导带与第二电荷转移材料的LUMO或导带偏移大于约0.2eV。导电材料可以可选地设置在纳米结构模板和第一电荷转移材料之间。
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