首页> 外国专利> Method for purifying tetrakis (fluoroaryl) borate / halide magnetic, tetrakis (fluoroaryl) borate / ether and process for preparing the same, and process for preparing tetrakis (fluoroaryl) borate.

Method for purifying tetrakis (fluoroaryl) borate / halide magnetic, tetrakis (fluoroaryl) borate / ether and process for preparing the same, and process for preparing tetrakis (fluoroaryl) borate.

机译:磁性四(氟芳基)硼酸酯/卤化物,四(氟芳基)硼酸酯/醚的纯化方法及其制备方法和制备四(氟芳基)硼酸酯的方法。

摘要

Process for purifying AR4 BMGX comprising treating a halide of TERAKIS (fluoroaryl) borate / magnesium (AR4 BMGX) with (1) the salt of an alkaline earth metal carboxylic acid, (2) an acid, (3) an acid and Subsequently, an alkaline earth metal hydroxide, or (4) an acid and then an alkaline earth metal salt of a carboxylic acid and process for preparing a derivative of TERAKIS (fluoroaryl) borate (AR4 BZ) BASED REACT WITH THE AR4 BMGX A COMPOUND CAPABLE OF GENERATING SPECIES monovalent cation. Said purification process ALLOWS separating and removing impurities in AR4 BMGX a simple and effective way. The invention also provides a complex of TERAKIS (fluoroaryl) borate / ETHER, A PROCESS FOR THE PREPARATION THEREOF, AND TO PREPARE A DERIVATIVE OF TERAKIS (FLUOROAIRL) BORO (AR4 BZ) PROCESS USING THE COMPLEX ETHER AND CAPABLE COMPOUND SPECIES GENERATING monovalent cation as compounds initials. THE ether complex can be easily purified to a high purity level SO WELL appropriate INTERMEDIATE FOR THE PREPARATION OF VARIOUS DERIVED TERAKIS (fluoroaryl) borates.
机译:纯化AR4 BMGX的方法,包括用(1)碱土金属羧酸的盐,(2)酸,(3)酸和随后的碱处理TERAKIS(氟芳基)硼酸镁/镁(AR4 BMGX)的卤化物。碱土金属氢氧化物,或(4)酸,然后是羧酸的碱土金属盐,以及制备基于AR4 BMGX的TERAKIS(氟代芳基)硼酸酯(AR4 BZ)的衍生物的方法可以合成的物种一价阳离子。所述纯化方法允许以简单有效的方式分离和去除AR4 BMGX中的杂质。本发明还提供了一种由TERAKIS(氟代芳基)硼酸酯/醚形成的络合物,其制备方法,以及使用生成单价阳离子的络合物和能合成的化合物制备了TERAKIS(氟代空气)BORO(AR4BZ)方法的衍生物。复合缩写。醚络合物可以很容易地纯化到高纯度水平,因此是制备各种衍生的terakis(氟代芳基)硼酸盐的合适中间体。

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