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Compound which performs non-resonant two-photon absorption, non-resonant two-photon light-emitting compound and non-resonant two-photon absorption induction method and process for emitting light thereby, optical data recording medium and process for recording data thereon, and two-photon polymerizable composition and process for polymerization thereof
Compound which performs non-resonant two-photon absorption, non-resonant two-photon light-emitting compound and non-resonant two-photon absorption induction method and process for emitting light thereby, optical data recording medium and process for recording data thereon, and two-photon polymerizable composition and process for polymerization thereof
The present invention provides a two-photon light-emitting compound represented by formula (1), an optical data recording medium capable of recording data with a laser beam comprising a compound represented by formula (1) and a two-photon polymerizable composition photopolymerizable by two-photon absorption comprising a polymerizable monomer or polymerizable oligomer and at least a two-photon absorption material being a compound represented by formula (1): ;wherein X1 and X2 may be the same or different and each represent a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group; R1, R2, R3 and R4 each independently represent a hydrogen atom or substituent; some of R1, R2, R3 and R4 may be connected to each other to form at least one ring; and n and m each independently represent an integer of from 1 to 4, with the proviso that when n and m are 2 or more, the plurality of R1's, R2's, R3's, and R4's each may be the same or different. The present invention also provides a photopolymerization process which causes polymerization reaction utilizing two-photon or higher multiple photon absorption induced by irradiating the above polymerizable composition with laser beam having a wavelength longer than the linear absorption band of the compound of the formula (1) and free of linear absorption.
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