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Production of activated charcoal beads for producing adsorbent, especially filter or protective material, comprising continuous carbonization of modified styrene-divinylbenzene polymer beads, batch pyrolysis and activation
Production of activated charcoal beads for producing adsorbent, especially filter or protective material, comprising continuous carbonization of modified styrene-divinylbenzene polymer beads, batch pyrolysis and activation
In the production of activated charcoal beads (I) by low temperature carbonization and activation of polymer beads based on styrene and divinyl benzene containing groups, which form free radicals on thermal decomposition and hence induce cross-linking, especially sulfonic acid (SO3H) groups, low temperature carbonization is started continuously, then pyrolyzed and activated discontinuously. Independent claims are also included for (a) (I) produced as above, especially with an intrinsic surface area of 800-1500, preferably 900-1200 m2/g, diameter of 0.2-1.0, preferably 0.3-0.8 mm, with a root mean square value of 0.4-0.6 mm, a bursting pressure of 5-20 N/bead and/or a jarred density of 400-800, preferably 500-750 g/l; (b) adsorbent materials containing (I), especially filters and protective materials, for the specified uses.
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机译:在通过低温碳化和活化基于含苯乙烯和二乙烯基苯的基团的聚合物珠的活化炭珠(I)的生产中,这些基团在热分解时会形成自由基并因此引起交联,尤其是磺酸(SO3H)基团,低温碳化是连续开始的,然后不连续地热解和活化。对于如上生产的(a)(I),也包括独立权利要求,特别是其固有表面积为800-1500,优选900-1200m 2 / g,直径为0.2-1.0,优选0.3-0.8mm。均方根值为0.4-0.6 mm,破裂压力为5-20 N /珠,和/或震击密度为400-800,优选为500-750 g / l; (b)含有(I)的吸附材料,特别是特定用途的过滤器和保护材料。
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