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An organic montmorillonite for polymer nano-composite and polymer nano-composite materials

机译:用于聚合物纳米复合材料和聚合物纳米复合材料的有机蒙脱土

摘要

PURPOSE: Organic montmorillonite is provided which is obtained by replacing the surface of montmorillonite with a nucleating organizing agent having nucleating function capable of inducing crystallization of polymer, and a polymer nanocomposite using the organic montmorillonite. CONSTITUTION: In organic montmorillonite which is obtained by cation substitution reaction using a Na-montmorillonite organizing agent, the organic montmorillonite is characterized in that the organizing agent is a nucleating organizing agent obtained from diisocyanate and polymer nucleating agent, wherein diisocyanate is one or more compounds selected from the group consisting of methylene bisphenyl isocyanate, 1,4-diisocyanatobutane, 1,6-diisocyanatohexane, 1,8-diisocyanatooctane, and 1,4-phenylene diisocyanate, the polymer nucleating agent is has a sorbitol group or xylitol group represented as in the following chemical formula 1: £Chemical Formula 1| where p is 0 or 1, n is 0 to 3, R is an alkyl group having 1 to 8 carbon numbers, an alkoxy group having 1 to 4 carbon numbers, a hydroxy group, a halogen group, alkyl having 1 to 8 carbon numbers-alkylthio group having 1 to 6 carbon numbers, and an alkylsulfoxy group having 1 to 8 carbon numbers.
机译:用途:提供一种有机蒙脱石,其是通过将蒙脱石的表面替换为具有成核功能的成核剂,该成核剂能够诱导聚合物的结晶,以及使用该有机蒙脱石的聚合物纳米复合材料而获得的。组成:有机蒙脱土是通过使用钠-蒙脱土组织剂进行阳离子取代反应而获得的,该有机蒙脱土的特征在于该组织剂是由二异氰酸酯和聚合物成核剂获得的成核剂,其中二异氰酸酯是一种或多种化合物。聚合物成核剂选自由亚甲基双苯基异氰酸酯,1,4-二异氰酸根合丁烷,1,6-二异氰酸根合己烷,1,8-二异氰酸根合辛烷和1,4-亚苯基二异氰酸酯组成的组,该聚合物成核剂具有山梨醇基或木糖醇基,表示为在以下化学式1中:£化学式1 |其中p为0或1,n为0至3,R为碳数为1至8的烷基,碳数为1至4的烷氧基,羟基,卤素,碳数为1至8的烷基具有1至6个碳数的-烷硫基和具有1至8个碳数的烷基亚磺氧基。

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