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Pigment dispersions containing dispersants having pendent hydrophobic polymeric segments prepared by controlled radical polymerization

机译:含有分散剂的颜料分散体,该分散剂具有通过受控的自由基聚合制备的侧链疏水性聚合物链段

摘要

A pigment dispersion comprising pigment, an aqueous carrier selected from water and a mixture of water and at least one organic solvent, and a pigment dispersant is described. The pigment dispersant is prepared by polymerizing (i) at least one prepolymer having a radically polymerizable group, and (ii) at least one second monomer. The prepolymer is prepared by controlled radical polymerization, e.g., atom transfer radical polymerization, of at least one radically polymerizable first monomer. The second monomer forms a polymeric backbone segment of the pigment dispersant, and the prepolymer forms polymeric segments that are pendent to the backbone. The backbone segment of the pigment dispersant is hydrophilic, while at least a portion of each pendent polymeric segment is hydrophobic.
机译:描述了一种颜料分散体,其包含颜料,选自水和水与至少一种有机溶剂的混合物的水性载体和颜料分散剂。通过使(i)至少一种具有可自由基聚合的基团的预聚物和(ii)至少一种第二单体聚合来制备颜料分散剂。所述预聚物是通过至少一种可自由基聚合的第一单体的受控自由基聚合,例如原子转移自由基聚合而制备的。第二单体形成颜料分散剂的聚合物主链链段,并且预聚物形成悬垂于该主链的聚合物链段。颜料分散剂的主链段是亲水的,而每个侧链聚合物段的至少一部分是疏水的。

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