首页> 外国专利> Method of preparation of 2,2'-bis(diarylphosphino)-6,6'- bis(trifluoromethyl)-1,1'-biphenyl, transition metal complex using it as ligand, and optically active 3-hydroxybutanoic acid ester derivative or . beta.-butyrolactone

Method of preparation of 2,2'-bis(diarylphosphino)-6,6'- bis(trifluoromethyl)-1,1'-biphenyl, transition metal complex using it as ligand, and optically active 3-hydroxybutanoic acid ester derivative or . beta.-butyrolactone

机译:制备2,2'-双(二芳基膦基)-6,6'-双(三氟甲基)-1,1'-联苯,以其为配体的过渡金属配合物和旋光性3-羟基丁酸酯衍生物或制备方法。 β-丁内酯

摘要

A novel phosphine compound usable as a catalyst in various asymmetric synthetic reactions is disclosed. The compound is a 2,2'- bis(diarylphosphino)-6,6'-bis(trifluoromethyl)-1,1'-biphenyl of (1): ##STR1## where R is a phenyl group or a phenyl group substituted by lower alkyl group, lower alkoxy group, halogen atom, or lower haloalkyl group.
机译:公开了在各种不对称合成反应中可用作催化剂的新型膦化合物。该化合物是(1)的2,2'-双(二芳基膦基)-6,6'-双(三氟甲基)-1,1'-联苯基:其中R是苯基或苯基被低级烷基,低级烷氧基,卤素原子或低级卤代烷基取代。

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