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Method for producing thin films by low temperature plasma- enhanced chemical vapor deposition using a rotating susceptor reactor

机译:使用旋转基座反应器通过低温等离子体增强化学气相沉积生产薄膜的方法

摘要

A method for depositing a film on a substrate by plasma- enhanced chemical vapor deposition at temperatures substantially lower than conventional thermal CVD temperatures comprises placing a substrate within a reaction chamber and exciting a first gas upstream of the substrate to generate activated radicals of the first gas. The substrate is rotated within the deposition chamber to create a pumping action which draws the gas mixture of first gas radicals to the substrate surface. A second gas is supplied proximate the substrate to mix with the activated radicals of the first gas and the mixture produces a surface reaction at the substrate to deposit a film. The pumping action draws the gas mixture down to the substrate surface in a laminar flow to reduce recirculation and radical recombination such that a sufficient amount of radicals are available at the substrate surface to take part in the surface reaction. Another method utilizes a gas-dispersing showerhead that is biased with RF energy to form an electrode which generates activated radicals and ions in a concentrated plasma close to the substrate surface. The activated plasma gas radicals and ions utilized in the invention contribute energy to the surface reaction such that the film may be deposited at a substantially lower deposition temperature that is necessary for traditional thermal CVD techniques. Furthermore, the activation of these species reduces the temperature needed to complete the surface reaction. The method is particularly useful in depositing titanium-containing films at low temperatures.
机译:一种通过在实质上低于常规热CVD温度的温度下通过等离子体增强化学气相沉积在基板上沉积膜的方法,该方法包括将基板置于反应室内,并在基板上游激发第一气体以产生第一气体的活化自由基。 。衬底在沉积室内旋转以产生泵送作用,该泵送作用将第一气体自由基的气体混合物吸引到衬底表面。在衬底附近供应第二气体,以与第一气体的活化自由基混合,并且该混合物在衬底上产生表面反应以沉积膜。泵送动作将气体混合物以层流的形式向下拉至基底表面,以减少再循环和自由基的重新结合,从而使足够量的自由基可用于基底表面以参与表面反应。另一种方法是利用分散有射频能量的气体喷淋头来形成电极,该电极在靠近基板表面的浓缩等离子体中产生活化的自由基和离子。本发明中使用的活化的等离子体气体自由基和离子为表面反应贡献能量,使得可以在较低的沉积温度下沉积膜,这是传统热CVD技术所必需的。此外,这些物质的活化降低了完成表面反应所需的温度。该方法在低温下沉积含钛膜时特别有用。

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