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Production manner null of the fumaric acid which uses the catalytic converter and this catalytic converter for fumaric acid production

机译:使用催化转化器的富马酸的生产方式及该催化转化器用于富马酸的生产

摘要

PURPOSE: To provide a catalyst for producing fumaric acid by the isomerization of maleic acid and a method for producing a high quality fumaric acid efficiently using the catalyst. ;CONSTITUTION: The catalyst for producing fumaric acid contains (A) a bromate and (B) at least one kind of thiourea compound selected from among thiourea and its derivatives as indispensable components. In addition, the catalyst can also contain at least one kind of water soluble metal salt selected from among the water soluble salts of cerium, copper, manganese, and iron. Fumaric acid is produced by the isomerization of maleic acid in the presence of the catalyst. In spite of the addition of a small amount of the catalyst, the isomerization reaction of maleic acid can be conducted at a high conversion ratio at a relatively low temperatures of 100°C or lower. Besides, fumaric acid obtained contains only a small amount of unreacted maleic acid and by-produced malic acid, is colorless, and has good thermal stability.;COPYRIGHT: (C)1996,JPO
机译:目的:提供一种通过马来酸异构化生产富马酸的催化剂,以及使用该催化剂有效生产高质量富马酸的方法。 ;组成:制备富马酸的催化剂含有(A)溴酸盐和(B)至少一种选自硫脲及其衍生物的硫脲化合物作为必不可少的组分。另外,该催化剂还可以包含选自铈,铜,锰和铁的水溶性盐中的至少一种水溶性金属盐。富马酸是在催化剂存在下通过马来酸异构化生产的。尽管加入少量催化剂,马来酸的异构化反应仍可以在100℃或更低的较低温度下以高转化率进行。此外,所获得的富马酸只含有少量未反应的马来酸和副产的苹果酸,无色,并且具有良好的热稳定性。;版权所有:(C)1996,日本特许厅

著录项

  • 公开/公告号JP2824394B2

    专利类型

  • 公开/公告日1998-11-11

    原文格式PDF

  • 申请/专利权人 株式会社日本触媒;

    申请/专利号JP19940163492

  • 发明设计人 薮内 輝明;上野 晃嗣;赤沢 陽治;

    申请日1994-07-15

  • 分类号B01J31/02;B01J27/08;C07C51/353;C07C57/15;

  • 国家 JP

  • 入库时间 2022-08-22 02:29:11

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