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Transition metal bleach activators for bleaching agents and detergent- bleach compositions

机译:过渡金属漂白活化剂,用于漂白剂和洗涤剂-漂白剂组合物

摘要

Transition metal containing composition for use as a bleach catalyst comprising at least one transition metal ion coordinated with at least one chelating ligand to form a complex capable of binding O.sub.2 H. sup.-. The ligand(s) should have at least two strong donor functional groups capable of coordinating with a single one of the transition metal ions in the complexes to form a six-member or larger ring. The complexes are capable of coordinating peroxide groups while the ligand functions to substantially prevent precipitation of hydroxides of the transition metal ions in aqueous alkaline solutions of the transition metal containing composition. A detergent-bleach composition comprising an effective amount of a peroxide bleaching agent and an effective amount of the bleach catalyst described above, and a bleaching agent composition comprising a peroxide compound present in an amount effective to impart a bleaching action and a catalyst present in an effective amount to promote the bleaching action of the peroxide compound comprising the transition metal composition described above are also disclosed, as well as a catalyst present in an effective amount to promote the bleaching action of peroxide compounds in a detergent-bleach composition comprising the transition metal composition described above.
机译:用作漂白催化剂的含过渡金属的组合物,其包含与至少一种螯合配体配位的至少一种过渡金属离子,以形成能够结合O 2 H. sup.-的络合物。配体应具有至少两个能与配合物中的一个过渡金属离子配位以形成六元或更大环的强供体官能团。该配合物能够配位过氧化物基团,而配体的作用是基本上防止过渡金属离子的氢氧化物在含过渡金属的组合物的碱性水溶液中沉淀。洗涤剂-漂白组合物,其包含有效量的过氧化物漂白剂和有效量的上述漂白催化剂,以及漂白剂组合物,其包含以有效赋予漂白作用的量存在的过氧化物化合物和存在于其中的催化剂。还公开了有效量的促进上述包含过渡金属组合物的过氧化物化合物的漂白作用,以及以有效量促进在包含过渡金属的洗涤剂-漂白组合物中的过氧化物化合物的漂白作用的催化剂。上述组成。

著录项

  • 公开/公告号US5720897A

    专利类型

  • 公开/公告日1998-02-24

    原文格式PDF

  • 申请/专利权人 UNIVERSITY OF FLORIDA;

    申请/专利号US19950377380

  • 发明设计人 XU CHENG;RUSSELL S. DRAGO;

    申请日1995-01-25

  • 分类号C01B15/04;C08F4/42;

  • 国家 US

  • 入库时间 2022-08-22 02:40:08

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