首页> 外国专利> CATHODIC DISBONDMENT RESISTANT EPOXY POWDER COATING COMPOSITION AND REINFORCING STEEL BAR COATED THEREWITH

CATHODIC DISBONDMENT RESISTANT EPOXY POWDER COATING COMPOSITION AND REINFORCING STEEL BAR COATED THEREWITH

机译:耐阴极脱胶的环氧树脂粉末涂料组合物及其上的钢筋

摘要

A thermosetting epoxy resin powder coating composition is provided that comprises an epoxy resin composed of a diglycidyl ether of bisphenol A, a curing agent composed of a bisphenol A endcapped diglycidyl ether of bisphenol A, and a cure catalyst composed of an imidazole adducted to a diglycidyl ether of bisphenol A, in which the ratio of curing agent to epoxy resin is below 70% stoichiometry, and preferably between about 10% and 60%stoichiometry. The thermosetting epoxy resin powder coating composition not only exhibits the desired flexibility and fast cure speeds, but also exhibits superior adhesion and superior resistance to delamination and cathodic disbondment, preferably having cathodic disbondment values typically less than 4 mm radial disbondment, and preferably less than 2 mm radial disbondment. Such properties are highly advantageous for protective powder coatings used on rebars and pipelines. The marked improvement in adhesion combined with good flow out behavior provide the thermosetting epoxy resin powder coating composition with the ability to effectively adhere to steel strappings and other dirty, oily and scaly metallic substrates. The thermosetting epoxy resin powder coating composition also begins to cure at very low temperatures for acceptable oven bake times. This property is highly advantageous for protective and decorative powder coatings used on wood and other heat sensitive substrates.
机译:提供了一种热固性环氧树脂粉末涂料组合物,其包含由双酚A的二缩水甘油醚组成的环氧树脂,由双酚A的双酚A封端的二缩水甘油醚组成的固化剂和由加到二缩水甘油基上的咪唑组成的固化催化剂。双酚A的醚,其中固化剂与环氧树脂的比率低于化学计量的70%,优选在约10%至60%之间。该热固性环氧树脂粉末涂料组合物不仅表现出所需的柔韧性和快速的固化速度,而且表现出优异的粘合性和优异的抗分层和阴极剥离的能力,优选具有通常小于4mm径向剥离,优选小于2的阴极剥离值。毫米径向剥离。这样的性能对于用于钢筋和管道的保护性粉末涂料非常有利。粘合性的显着改善与良好的流出性能相结合,为热固性环氧树脂粉末涂料组合物提供了有效粘合钢带和其他肮脏,油性和鳞片状金属基材的能力。热固性环氧树脂粉末涂料组合物也开始在非常低的温度下固化可接受的烤箱烘烤时间。对于在木材和其他热敏性基材上使用的保护性和装饰性粉末涂料而言,该性能非常有利。

著录项

  • 公开/公告号CA2206481A1

    专利类型

  • 公开/公告日1997-12-28

    原文格式PDF

  • 申请/专利权人 MORTON INTERNATIONAL INC.;

    申请/专利号CA19972206481

  • 发明设计人 CORRELL GLENN D.;BERSTLER ROY M.;

    申请日1997-05-29

  • 分类号C09D163/02;C09D5/08;C09D5/46;

  • 国家 CA

  • 入库时间 2022-08-22 02:54:14

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