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Simplified process for producing alkenyl succinimides or poly(alkenyl succinimides)

机译:制备烯基琥珀酰亚胺或聚(烯基琥珀酰亚胺)的简化方法

摘要

The preparation of an alkenyl succinimide or polyalkenyl succinimide comprises: (a) the preparation of an alkenyl- or polyalkenylsuccinic anhydride by reaction between an olefin or a polyolefin with unsaturated dicarboxylic acid anhydride, e.g. maleic anhydride or substituted maleic anhydride with one or two methyl groups at 150-300 degrees C, in an aromatic solvent, e.g. toluene or xylenes in a ratio of 30-70 wt.% w.r.t. the reaction mixture, in which a fraction of the unsaturated dicarboxylic acid anhydride does not react with the olefin or the polyolefin; (b) reaction of the unreacted unsaturated dicarboxylic acid anhydride from step (a) with alcohol or amine, at a temperature from ambient temperature to the b. pt. of the solvent; and (c) reaction of the resulting product from step (b) with an amine.
机译:链烯基琥珀酰亚胺或聚链烯基琥珀酰亚胺的制备包括:(a)通过烯烃或聚烯烃与不饱和二羧酸酐,例如烯丙基的反应,制备链烯基或聚链烯基琥珀酸酐。在芳族溶剂,例如芳族溶剂中,在150-300℃下具有一个或两个甲基的马来酸酐或取代的马来酸酐。甲苯或二甲苯的比例为w.r.t的30-70 wt。%反应混合物,其中一部分不饱和二羧酸酐不与烯烃或聚烯烃反应; (b)在环境温度至b的温度下,使步骤(a)的未反应的不饱和二羧酸酐与醇或胺反应。点溶剂(c)由步骤(b)得到的产物与胺反应。

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