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METHOD FOR ANALYZING AB5 HYDROGEN STORING ALLOY FOR MAIN COMPONENT

机译:主要成分的AB5贮氢合金的分析方法

摘要

PURPOSE: To analyze an AB5 hydrogen storing alloy with high accuracy by respectively determining rare-earth elements after separating the rare-earth elements from ordinary elements by using a cation exchange resin and determining each ordinary element after separating the ordinary elements from each other by using an anion exchange resin. CONSTITUTION: The A of a AB5 hydrogen storing on alloy is composed at least of one element selected from among the group of La, Ce, Pr, and Nd and the B is composed at least of one element selected from among the group of Al, Co, Mn, and Ni. The alloy is dissolved in an oxidizing acid, such as the aqua regia, etc. When a solution prepared by diluting the aqua regia dissolving the AB5 is passed through a column of a cation exchange resin, the resin adsorbs both the rare-earth and ordinary elements. When the column is washed with a hydrochloric acid, etc., the adsorbed ordinary and rare-earth elements are eluted in the solution. Therefore, the rare-earth elements can be determined. Similarly, the ordinary elements are adsorbed to an anion exchange resin and the elements are separately determined after separating the elements from each other.
机译:目的:通过使用阳离子交换树脂将稀土元素与普通元素分离后分别测定稀土元素,并通过将普通元素彼此分离后确定每种普通元素,从而对AB5储氢合金进行高精度分析。阴离子交换树脂。组成:合金中存储的AB5氢的A至少由选自La,Ce,Pr和Nd的一种元素组成,而B则至少由选自Al的一种元素组成, Co,Mn和Ni。将该合金溶解在王水等氧化性酸中。通过将溶解AB5的王水稀释而制成的溶液通过阳离子交换树脂柱时,该树脂会吸附稀土和普通稀土。元素。当用盐酸等洗涤柱子时,吸附的普通和稀土元素被洗脱在溶液中。因此,可以确定稀土元素。类似地,普通元素被吸附到阴离子交换树脂上,并且在将元素彼此分离之后分别确定元素。

著录项

  • 公开/公告号JPH095314A

    专利类型

  • 公开/公告日1997-01-10

    原文格式PDF

  • 申请/专利权人 SHIN ETSU CHEM CO LTD;

    申请/专利号JP19950180962

  • 发明设计人 YAMAGUCHI HIDENAO;YAMASHITA YOSUKE;

    申请日1995-06-23

  • 分类号G01N30/88;C22C19/00;G01N33/20;H01M4/38;

  • 国家 JP

  • 入库时间 2022-08-22 03:31:16

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