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HETEROCYCLIC OXYBENZYLIDENEHYDRAZINE COMPOUND, ITS PRODUCTION AND VERMIN CONTROLLING AGENT FOR AGRICULTURAL AND HORTICULTURAL USE

机译:用于农,园艺业的杂环氧苄基二氢联苯胺化合物及其生产和害虫控制剂

摘要

PURPOSE: To obtain a new compound useful as a vermin controlling agent for agricultural and horticultural use such as insecticide. ;CONSTITUTION: This compound is expressed by formula I [R1 is phenyl; R2 is H; R3 is H, an alkoxycarbonyl or an acyl; R2 and R3 may together with N form N=CR4NR5R6 (R4 to R6 are each an alkyl); Q is a 6-membered ring containing 1-3 N atoms], e.g. 4-chloro-4'-(5-chloro-6-methyl-4-pyrimidinyloxy) benzophenone 1-dimethylaminoethylidenehydrazone. The compound of formula I can be produced by reacting a compound of formula II with a compound of formula Z-Q (Z is an eliminable group) in the presence of a base (e.g. potassium carbonate) in a solvent (e.g. N,N-dimethylformamide) for 0.3-24hr at a temperature below the boiling point of the system. The amount of the compound of formula Z-Q is 0.5-2mol based on 1mol of the compound of formula II. The compound is effective for the control of agricultural and horticultural vermin such as diamondback moth and common cutworm, stored grain vermin such as flattened rustred flour beetle and agricultural and horticultural pathogen such as leaf rust of wheat.;COPYRIGHT: (C)1996,JPO
机译:目的:获得一种新型化合物,用作杀虫剂等农业和园艺用途的害虫防治剂。 ;组成:该化合物由式I表示[R 1 为苯基; R 2 是H; R 3 为H,烷氧羰基或酰基; R 2 和R 3 可以与N一起形成N = CR 4 NR 5 R 6 < / Sup>(R 4 至R 6 均为烷基); Q是含有1-3个N原子的6元环。 4-氯-4'-(5-氯-6-甲基-4-嘧啶氧基)二苯甲酮1-二甲基氨基乙叉hydr。式I的化合物可通过在溶剂(例如N,N-二甲基甲酰胺)中在碱(例如碳酸钾)存在下使式II的化合物与式ZQ的化合物(Z是可消除的基团)反应来制备。在低于系统沸点的温度下放置0.3-24小时。相对于1摩尔式II化合物,式Z-Q化合物的量为0.5-2摩尔。该化合物可有效控制农业和园艺害虫,例如小菜蛾和普通地老虎,贮藏的谷物害虫,例如扁平的锈皮粉甲虫和农业和园艺病原体,例如小麦的叶锈病。;版权所有:(C)1996,JPO

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