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Organically superconducting materials and processes for their preparation.
Organically superconducting materials and processes for their preparation.
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机译：有机超导材料及其制备方法。
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摘要
PURPOSE:To enable obtaining an organic superconducting material of easy workability for forming the shape of a fabric, a film and the like by dispersing an organic superconductor comprising an electron doner and acceptor into polymer. CONSTITUTION:Electron donor and acceptor materials dissolved and diffused in a solvent are oxidized and reduced electrochemically, thereby synthesizing an organic superconductor. Then, an unreacted electron donor material, an unreacted electron acceptor material and the solvent after the completion of a reaction process are removed under coexistence with polymer. As the organic superconductor, (TMTSF)2X1 (TMTSF is tetramethyl tetraselenafulvaren, and X1 is ClO4 and the like) is exemplified. The type of the polymer is not limited specifically, so far as soluble or swelling in the solvent used. As a result, it is possible to enhance superconducting characteristics and increase the mechanical strength of the material when the polymer is shaped into a fabric form and a film form and the like, and drawn for the orientation of crystallized polymer molecules.
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机译：目的：通过将包含电子给体和受体的有机超导体分散到聚合物中，从而能够获得易于加工的有机超导材料，以形成织物，薄膜等形状。组成：溶解和扩散在溶剂中的电子供体和受体材料被电化学氧化和还原，从而合成有机超导体。然后，在与聚合物共存的情况下，除去反应完成后的未反应的电子给体材料，未反应的电子受体材料和溶剂。作为有机超导体，可例举（TMTSF）2 X 1（TMTSF为四甲基四硒富勒烯，X 1为ClO 4等）。聚合物的类型没有特别限制，只要在所用溶剂中可溶或溶胀即可。结果，当将聚合物成形为织物形式和膜形式等并拉伸以结晶聚合物分子的取向时，可以增强超导特性并提高材料的机械强度。
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