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Multi:metal oxide useful as catalyst esp. in gas phase oxidn. of acrolein to acrylic acid

机译：多种：金属氧化物尤其可用作催化剂。在气相中被氧化。丙烯醛制丙烯酸

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Multimetal oxide compsn. of formula (I) is new: (A)p (B)q (I): A = Mo12VaX1bX2cX3dX4eX5fX6gOx (co-phase); B = X712CuhHiOy (key phase); X1 = W, Nb, Ta, Cr and/or Ce; X2 = Cu, Ni, Co, Fe, Mn and/or Zn; X3 = Sb and/or Bi; X4 = Li, Na, K, Rb, Cs and/or H; X5 = Mg, Ca, Sr and/or Ba; X6 = Si, Al, Ti and/or Zr; X7 = Mo, W, V, Nb and/or Ta; a = 1-8; b = 0.2-5; c = 0-23; d, g = 0-50; e = 0-2; f = 0-5; h = 4-30; i = 0-20; x, y = values depending on the valency and content of elements other than O; p, q = values other than O, with the ratio p/q = 160:1 to 1:1. The A and B fractions are each in the form of 30 zones, which differ in chemical compsn. from their local surroundings, and the relative distribution of the A and B zones is as in a mixt. of finely-divided A and finely-divided B. Also claimed are multimetal oxide compsns. of wolframite structural type, of formulae (II), (III), (IV) and (V): in (II), 1/(A+B+C+D+E) = 0.7-1.3; F = 0-1; and B+C+D+E = over 0 to 1. In (III), 1/(A+B+C) = 0.7-1.3; A, B, C all = more than O and B+C = at most 1; In (IV), 1/(A+B) = 0.7-1.3; A, B both = more than O and B = at most 1; In (V), 1/(A+C) = 0.7-1.3; A, C both more than O and C at most 1.

机译：多金属氧化物复合物。式（I）的式子是新的：（A）p（B）q（I）：A = Mo12VaX 1 bX 2 cX 3 3 dX 4 eX 5 fX 6 gOx（co-相）; B = X 7 12 CuhHiOy（关键相）; X 1 ＝ W，Nb，Ta，Cr和/或Ce; X 2 ＝ Cu，Ni，Co，Fe，Mn和/或Zn;和X 3 ＝ Sb和/或Bi; X 4 ＝ Li，Na，K，Rb，Cs和/或H; X 5 ＝ Mg，Ca，Sr和/或Ba; X 6 ＝ Si，Al，Ti和/或Zr; X 7 ＝ Mo，W，V，Nb和/或Ta; a = 1-8; b = 0.2-5; c = 0-23; d，g = 0-50; e = 0-2; f = 0-5; h = 4-30; i = 0-20; x，y =取决于O以外的元素的价和含量的值; p，q = O以外的值，比率p / q = 160：1到1：1。 A和B馏分分别以30个区域的形式存在，其化学成分不同。从它们周围的环境来看，A和B区域的相对分布就像混合。还要求保护的是细分的A和细分的B。还要求保护多金属氧化物化合物。式（II），（III），（IV）和（V）的黑钨矿结构类型：在（II）中，1 /（A + B + C + D + E）＝ 0.7-1.3; F = 0-1;并且B + C + D + E ＝ 0至1。在（III）中，1 /（A + B + C）＝ 0.7-1.3; A，B，C全部=大于O，并且B + C =最多1;在（IV）中，1 /（A + B）= 0.7-1.3; A，B都等于O，B最多为1;在（V）中，1 /（A + C）= 0.7-1.3; A，C最多比O和C多1。

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公开/公告号DE4440891A1

专利类型
公开/公告日1996-05-23

原文格式PDF
申请/专利权人 BASF AG 67063 LUDWIGSHAFEN DE;
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申请/专利号DE19944440891
发明设计人 TENTEN ANDREAS DR. 67434 NEUSTADT DE;MAROSI LASZLO DR. 67063 LUDWIGSHAFEN DE;KOHL VERONIKA DR. 64295 DARMSTADT DE;MARTIN FRIEDRICH-GEORG DR. 69115 HEIDELBERG DE;HIBST HARTMUT DR. 69198 SCHRIESHEIM DE;
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申请日1994-11-17
分类号C01G1/02;C07C57/055;C01G41/00;B01J21/00;C01G39/00;B01J23/00;
国家 DE
入库时间 2022-08-22 03:42:11

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