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Process for the production of a multicoat coating, aqueous coating compositions, water-thinnable polyacrylate resins and process for the production of water-thinnable polyacrylate resins

机译:生产多层涂料,水性涂料组合物,水可稀释的聚丙烯酸酯树脂的方法和水可稀释的聚丙烯酸酯树脂的生产方法

摘要

The invention relates to a process for the production of a multicoat coating in which an aqueous transparent topcoat composition containing a polyacrylate resin as binder is employed. The polyacrylate resin can be obtained by adding, either successively or alternately in part amounts, a mixture of a carboxyl-containing ethylenically unsaturated monomer (a1) and a monomer (a2) free from carboxyl groups and a mixture (b) consisting of (meth)acrylic acid esters which are free from carboxyl groups, of hydroxyl-containing ethylenically unsaturated monomers and, if appropriate, of other ethylenically unsaturated monomers to an organic solvent and carrying out a polymerization in the presence of a radical- forming initiator and, at the end of the polymerization, neutralizing the resultant polyacrylate resin and dispersing it in water. The type and amount of (a1), (a2) and (b) are chosen so that the polyacrylate resin has a hydroxyl value of 40 to 200, an acid value of 20 to 100 and a glass transition temperature (T.sub.G) of -40° C. to + 60° C.
机译:本发明涉及一种多层涂层的生产方法,其中采用了一种含有聚丙烯酸酯树脂作为粘合剂的水性透明面漆组合物。聚丙烯酸酯树脂可以通过依次或部分地添加含羧基的烯键式不饱和单体(a1)和无羧基的单体(a2)的混合物与由(甲基)构成的混合物(b)而得到。含羧基的烯键式不饱和单体和(如果合适)其他烯键式不饱和单体的不含羧基的丙烯酸酯与有机溶剂的混合物,并在形成自由基的引发剂存在下进行聚合在聚合反应结束时,中和所得的聚丙烯酸酯树脂并将其分散在水中。选择(a1),(a2)和(b)的类型和量,以使聚丙烯酸酯树脂具有40至200的羟值,20至100的酸值和玻璃化转变温度(TG)。 )-40°C至+ 60°C

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