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Substituted fluorine-containing -indole butyric acid and plant growth regulating agent containing it as an active ingredient

机译:取代的含氟吲哚丁酸和以其为有效成分的植物生长调节剂

摘要

PURPOSE: To obtain the subject new compounds, having physiological activities in remarkably elongating roots of plants and useful as a plant growth regulator. ;CONSTITUTION: These compounds are expressed by formula I [Y is OH, an alkoxy or an (alkyl)amino; R1 and R2 are each a halogen, an alkyl, an alkoxy, an aryl, nitro, an (alkyl)amino or H], e.g. 4,4,4-trifluoro-3-(2-methylindol-3-)butyric acid. The compounds expressed by formula I in which Y is the OH are obtained by reacting compounds expressed by formula II with a previously prepared reational product of diethyl malonate with metallic Na, providing compounds expressed by formula III (Et is ethyl) and then thermally refluxing the resultant compound with K2CO3. The compounds expressed by formula I in which Y is the alkoxy are prepared by esterifying the resultant compounds and the compounds expressed by formula I in which Y is the (alkyl)amino are obtained by reacting the prepared compounds with an (alkyl)amine.;COPYRIGHT: (C)1995,JPO
机译:目的:为了获得主题的新化合物,其在植物的根部显着伸长中具有生理活性,并可用作植物生长调节剂。 ;组成:这些化合物由式I表示[Y为OH,烷氧基或(烷基)氨基; R 1 和R 2 分别是卤素,烷基,烷氧基,芳基,硝基,(烷基)氨基或H],例如。 4,4,4-三氟-3-(2-甲基吲哚-3-)丁酸。通过使式II表示的化合物与先前制备的丙二酸二乙酯的阳离子产物与金属Na反应,得到式III表示的化合物(Et为乙基),然后将其热回流,得到式I表示的化合物,其中Y为OH。生成的化合物具有K 2 CO 3 。式Ⅰ中Y为烷氧基的化合物是通过酯化所得化合物而制得的,式中Y是(烷基)氨基的式Ⅰ化合物是将制得的化合物与(烷基)胺反应制得的。版权所有:(C)1995,日本特许厅

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