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Nonlinear optical materials, method of manufacturing the same, and optical wavelength converter

机译:非线性光学材料,其制造方法以及光学波长转换器

摘要

The invention provides a nonlinear optical material comprising a compound represented by the general formula (1): ##STR1## wherein R.sup. 1 denotes an electron attractive group, R.sup.2 denotes a group selected from the group consisting of a hydrogen atom, methyl group, methoxy group and electron attractive group, R.sup.3 denotes a straight-chain alkylene group, and X denotes an oxygen or sulfur atom. The invention also relates to a method of manufacturing a nonlinear optical material comprising the steps of dissolving a compound represented by the general formula (1) in an organic solvent, and evaporating the solvent while keeping its temperature constant or lowering its temperature, thereby growing a crystal of the compound represented by the general formula (1). The nonlinear optical material of the invention possessing a molecular structure realized by linking structures having a strong electron attractive group and weak electron donative portion with straight-chain alkylene portions, and thus a nonlinear optical material having a shortened absorption edge wavelength and excellent crystallinity may be obtained. These nonlinear optical materials can be effectively utilized as the nonlinear optical material for an optical wavelength converter.
机译:本发明提供了一种非线性光学材料,其包含由通式(1)表示的化合物:其中R.sup。 1表示电子吸引基,R 2表示选自氢原子,甲基,甲氧基和电子吸引基的基团,R 3表示直链亚烷基,X表示氧或硫原子。本发明还涉及一种制造非线性光学材料的方法,该方法包括以下步骤:将通式(1)表示的化合物溶解在有机溶剂中,并且在保持其温度恒定或降低其温度的同时蒸发该溶剂,从而生长一种非线性光学材料。通式(1)表示的化合物的结晶。本发明的非线性光学材料具有通过将具有强电子吸引基和弱电子给体部分的结构与直链亚烷基部分连接而实现的分子结构,因此可以是吸收边波长缩短且结晶性优异的非线性光学材料。获得。这些非线性光学材料可以有效地用作光学波长转换器的非线性光学材料。

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