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Method for quantitative calibration of in situ optical chemical measurements in soils using soil class and characteristics

机译:利用土壤类别和特性对土壤中原位光学化学测量进行定量校准的方法

摘要

A method assures the quantitative or semiquantitative assessment of analytes in soils by in situ optical methods. A determination is made of the optical chemical response factors for chemicals of interest which are added in known amounts to discrete soil matrices (types) and conditions (moisture content) under controlled laboratory conditions to provide predetermined reference signals. A combination probe is provided with an optical chemical sensing device that produces chemical concentration signals representative of the concentration of a chemical of interest in a soil sample and further is provided with a strain gauge sensing device that produces strain gauge signals representative of soil type and optionally, condition of the soil sample. The combination probe is inserted into the soil sample and the optical chemical sensing device produces the chemical concentration signals and the optical strain gauge sensing device, simultaneously and in parallel, produces the optical strain gauge signals. The optical chemical concentration signals and strain gauge signals are fed to a processor where they are compared to the predetermined reference signals to arrive at an in situ quantification of chemicals of interest in the soil sample.
机译:一种方法可通过原位光学方法确保对土壤中分析物进行定量或半定量评估。确定感兴趣化学物质的光学化学响应因子,将其以已知的量添加到受控实验室条件下的离散土壤基质(类型)和条件(水分含量)中,以提供预定的参考信号。组合探头设有光学化学传感装置,该光学传感装置产生代表土壤样品中所关注化学物质浓度的化学浓度信号,并且还配备有应变仪传感装置,该应变仪传感装置产生代表土壤类型的应变仪信号,并可选地产生应变仪信号,土壤样品的状况。将组合探头插入土壤样品中,光学化学传感装置产生化学浓度信号,光学应变仪传感装置同时并行地产生光学应变仪信号。光学化学浓度信号和应变仪信号被馈送到处理器,在处理器中将其与预定参考信号进行比较,以实现对土壤样品中目标化学物质的现场定量。

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