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Poly (secondary amines) with controlled functional functional density and methods for their preparation

机译:具有受控功能官能密度的聚(仲胺)及其制备方法

摘要

The present invention relates to a process for the preparation of poly (secondary amines) having controlled functional functional densities comprising the steps of: (a) comprising reactive carbon-carbon double bonds, Contacting a polymer comprising olefinic unsaturation with carbon monoxide in hydrogen under hydroformylation reaction conditions in the presence of a hydroformylation reaction catalyst to produce a polyaldehyde having an impaired functional functional density; (b) preparing a poly (secondary amine) having a ratio of aldehyde groups to reactive carbon-carbon double bonds in the polyaldehyde substantially equal to the ratio of the secondary amine groups to the reactive carbon-carbon double bonds , Aliphatic or cycloaliphatic primary amines or aromatic primary amines which are sterically hindered with polyaldehyde are brought into contact under reductive amination conditions in the presence of alkali metal borohydride.
机译:本发明涉及具有受控功能官能密度的聚(仲胺)的制备方法,该方法包括以下步骤:(a)包含反应性碳-碳双键,在氢甲酰化下,使包含烯烃不饱和键的聚合物与一氧化碳在氢气中接触在加氢甲酰化反应催化剂的存在下的反应条件,以产生功能功能密度受损的多醛; (b)制备具有在醛中醛基与活性碳-碳双键之比基本上等于仲胺基与活性碳-碳双键之比的聚(仲胺),脂肪族或脂环族伯胺在碱金属硼氢化物的存在下,在还原胺化条件下,使在空间上受多醛阻碍的芳族伯胺或芳族伯胺接触。

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