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Para-aramid dope, para-aramid fiber, para-aramid pulp and process to produce para-aramid fiber and pulp

机译:对位芳纶纺丝原液,对位芳纶纤维,对位芳纶纸浆及其生产对位芳纶纤维和纸浆的方法

摘要

A para-aramide dope of low degree of polymerisation exhibiting an optical anisotropy containing 4-10% by weight of a para-aramide having an intrinsic viscosity of 1.0-2.5 dl/g and 2-10% by weight of an alkali metal chloride or an alkaline earth metal chloride in a polar amide solvent; a para-aramide fiber obtained by spinning the above-mentioned para-aramide dope of low degree of polymerization; a para-aramide pulp obtained by cutting the above-mentioned para-aramide fiber into a short fiber, mechanically fibrillating the short fiber with a high shearing force and thereafter drying the fibrillated short fiber; a process for producing a para-aramide fiber which comprises adding 0.94-0.99 mole of a para-oriented aromatic dicarboxylic acid halide per 1.00 mole of a para-oriented aromatic diamine in a polar amide solvent in which 2-10% by weight of an alkali metal chloride or an alkaline earth metal chloride is dissloved, carrying out a polymerization at a temperature of -20 DEG C to 50 DEG C to form a para-aramide dope of low degree of polymerization exhibiting an optical anisotropy and having a para-aramide concentration of 4-10% by weight, and spinning the dope; and a process for producing a para-aramide pulp which comprises cutting the above-mentioned para-aramide fiber into a short fiber, mechanically fibrillating the short fiber with a high shearing force, and thereafter drying the fibrillated short fiber.
机译:低聚合度的对位芳酰胺涂料,表现出光学各向异性,该光学各向异性包含4-10重量%的特性粘度为1.0-2.5 dl / g的对位芳酰胺和2-10%的碱金属氯化物或极性酰胺溶剂中的碱土金属氯化物;通过将上述低聚合度的对位芳族聚酰胺纺丝得到的对位芳族聚酰胺纤维。通过将上述对位芳族聚酰胺纤维切成短纤维,以高剪切力将其短纤化,然后干燥原纤化的短纤维,得到对位芳族聚酰胺纸浆。一种生产对位芳族聚酰胺纤维的方法,该方法包括在极性酰胺溶剂中每1.00摩尔对位芳族二胺加入0.94-0.99摩尔对位芳族二羧酸卤化物,其中2-10%(重量)除去碱金属氯化物或碱土金属氯化物,在-20℃至50℃的温度下进行聚合反应以形成低聚合度,表现出光学各向异性并具有对位芳酰胺的对位芳酰胺涂料。浓度为4-10重量%,并纺丝原液;制备对位芳族聚酰胺纸浆的方法,该方法包括将上述对位芳族聚酰胺纤维切成短纤维,以高剪切力将其短纤化,然后干燥原纤化的短纤维。

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