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SILK FIBROIN-GRAFT POLYMER-PROCESSED FABRIC AND ITS PRODUCTION

机译:丝素纤维接枝聚合物加工的织物及其生产

摘要

PURPOSE: To readily obtain silk fibroin-graft polymer-processed fabric having silk luster, handle, washing resistance, repulsion and water vapor absorption by forming a coating film comprising a specific amount of silk fibroin-graft polymer on the surface of a fiber. ;CONSTITUTION: An aqueous solution of silk fibroin is blended with a bifunctional monomer of formula I [R is directly bonded group of formula II, formula III, formula IV or CnH2n (n is 1-6); z is H or CH3; a and b are numbers to make a+b 0-50; x and y are numbers to make x+y 0-30 with the proviso that a+b+x+y≥10), a monomer containing OH, COOH, NH2, sulfo group or phosphate group [e.g. (meth)acrylic acid] and a monomer containing an aziridine group or a polyfunctional compound containing two or more aziridine groups to give a treating solution, Fabric of natural fiber or synthetic fiber is immersed in the treating solution, graft polymerization is carried out on the fabric to attach 0.1-5% owf silk fibroin and 0.2-10% pwf coating film comprising the silk fibroin-graft polymer to the fabric. The prepared fabric has luster and water vapor absorption close to those of silk and shows scroop feellng of characteristic silk.;COPYRIGHT: (C)1994,JPO&Japio
机译:目的:通过在纤维表面上形成包含一定量的丝纤蛋白接枝聚合物的涂膜,可以容易地获得具有丝光泽,手感,耐洗涤性,排斥性和水蒸气吸收性的丝纤蛋白接枝聚合物加工的织物。 ;构成:将丝素蛋白水溶液与式I的双功能单体混合[R是式II,式III,式IV或C n H 2n 的直接键合基团(n为1-6); z为H或CH 3 ; a和b是使a + b为0-50的数字; x和y是使x + y为0-30的数字,条件是a + b + x +y≥10),该单体为OH,COOH,NH 2 ,磺基或磷酸基[例如(甲基)丙烯酸]和含有氮丙啶基团的单体或含有两个或多个氮丙啶基团的多官能化合物以提供处理溶液,将天然纤维或合成纤维的织物浸入处理溶液中,在该溶液上进行接枝聚合。织物,以将0.1-5%的owf丝素蛋白和0.2-10%的pwf涂膜(包含丝素蛋白接枝聚合物)附着到织物上。所制得的织物具有接近真丝的光泽和水蒸气吸收性,并表现出特有真丝的色感觉。;版权所有:(C)1994,日本特许厅&日本apio

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