(a)1- indicates nitrate, cyanate, rhodanide, periodate, perchlorate, tetraphenyl borate, salicylate, thiosalicylate, O,O-di-C3-C8 alkyl dithiophosphate, C1-C8-alkyl xanthogenate, ICl2-, ICIBr-, IBr2-, Cl3-, Br3- or an N,N-dialkyl dithiocarbamate of formulawhereby each of the two residues A are C1-C8 alkyl or form the group -NA2 together with a pyrrolidino, piperidino, or morpholino residue;(Hb)1- is the hydrogen form of the anion (b)2-, and (b)2- indicates sulfate, carbonate, ethylene-bis- dithiocarbamate of the formula[Fe(CN)5(NO)]2-, (Fe(SCN)5(NO)]2-, or a complex anion [Me(L)4]2-, whereby Me stands for a zinc, copper or nickel atom, and L stands for cyanide or rhodanide;(H2c)1- and (Hc)2- are the dihydrogen and the hydrogen forms of the anion (c)3-, and (C)3- indicates phosphate [Cu(CN)4]3-, [Cu(SCN)4]3- or a complex anion[Me1(L)6]3-, whereby Me' stands for an iron, cobalt, or manganese atom, and L stands for cyanide or rhodanide; and(H3d)1-, (H2d)2- and (Hd)3- are the trihydrogen, dihydrogen, and hydrogen forms of the anion (d)4-, and (d)4- indicates a complex anion [Me'(L)6]4-, whereby Me' stands for an iron, cobalt, or manganese atom, and L stands for cyanide or rhodanide, with the prerequisite that in the case where Y = N, Xn- is not N,N-dialkyl dithiocarbamate, tetraphenyl borate, nitrate, hydrogen sulfate, sulfate, phosphate, hydrogen or dihydrogen phosphate, and with the further provision that if Y = P and at the same time Xn- = tetraphenyl borate, R1 is not phenyl.;The compounds can be used as biocides with broad biological action spectrum."/> Chemical compounds and salts of ammonio and fosfonio, composition,Process for the control of organisms on substrates or places chosen of materials technology and systems of water and process for protecting materials technology or systems of water from attack by organisThe harmful.
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Chemical compounds and salts of ammonio and fosfonio, composition,Process for the control of organisms on substrates or places chosen of materials technology and systems of water and process for protecting materials technology or systems of water from attack by organisThe harmful.

机译:铵盐和磷膦酸盐的化学化合物和盐的组成,在材料技术和水系统中选择的底物或场所上控制生物的过程以及保护材料技术或水系统不受有机物侵蚀的过程有害。

摘要

New compounds of formula (I)are described in which Y stands for a phosphorus or nitrogen atom, n indicates a number from 1-4 and corresponds to the valence of the anion Xn-, the residues R1 are the same or different, and in the case where Y = N, indicate C2-C4-alkyl or benzyl, and in the case where Y = P, have the meaning C3-C4 alkyl, phenyl or cyclohexyl, R2 represents C10-C14 alkyl, and Xn- indicates one of the anions (a)1-, (Hb)1-, (b)2-, (H2c)1-, (Hc)2-, (C)3-, (H3d)1-, (N2d)2-, (Hd)3- or (d)4-, whereby(a)1- indicates nitrate, cyanate, rhodanide, periodate, perchlorate, tetraphenyl borate, salicylate, thiosalicylate, O,O-di-C3-C8 alkyl dithiophosphate, C1-C8-alkyl xanthogenate, ICl2-, ICIBr-, IBr2-, Cl3-, Br3- or an N,N-dialkyl dithiocarbamate of formulawhereby each of the two residues A are C1-C8 alkyl or form the group -NA2 together with a pyrrolidino, piperidino, or morpholino residue;(Hb)1- is the hydrogen form of the anion (b)2-, and (b)2- indicates sulfate, carbonate, ethylene-bis- dithiocarbamate of the formula[Fe(CN)5(NO)]2-, (Fe(SCN)5(NO)]2-, or a complex anion [Me(L)4]2-, whereby Me stands for a zinc, copper or nickel atom, and L stands for cyanide or rhodanide;(H2c)1- and (Hc)2- are the dihydrogen and the hydrogen forms of the anion (c)3-, and (C)3- indicates phosphate [Cu(CN)4]3-, [Cu(SCN)4]3- or a complex anion[Me1(L)6]3-, whereby Me' stands for an iron, cobalt, or manganese atom, and L stands for cyanide or rhodanide; and(H3d)1-, (H2d)2- and (Hd)3- are the trihydrogen, dihydrogen, and hydrogen forms of the anion (d)4-, and (d)4- indicates a complex anion [Me'(L)6]4-, whereby Me' stands for an iron, cobalt, or manganese atom, and L stands for cyanide or rhodanide, with the prerequisite that in the case where Y = N, Xn- is not N,N-dialkyl dithiocarbamate, tetraphenyl borate, nitrate, hydrogen sulfate, sulfate, phosphate, hydrogen or dihydrogen phosphate, and with the further provision that if Y = P and at the same time Xn- = tetraphenyl borate, R1 is not phenyl.;The compounds can be used as biocides with broad biological action spectrum.
机译:式(I)的新化合物描述了其中Y代表磷或氮原子,n表示1-4的数字,并对应于阴离子X n-的化合价,残基R 1 相同或不同,在Y = N的情况下,表示C 2 -C 4 -烷基或苄基,在Y = P的情况下,具有C 3 -C 4 烷基,苯基或环己基的含义,R 2 表示C 10 -C < Sub> 14 烷基和X n-表示阴离子之一(a) 1-,(Hb) 1- ,(b) 2-,(H 2 c) 1-,(Hc) 2-,( C 3-,(H 3d 1-,(N 2d 2-,(Hd) 3-或(d) 4- (a) 1-表示硝酸盐,氰酸盐,罗丹酸盐,高碘酸盐,高氯酸盐,四苯基硼酸盐,水杨酸盐,硫代水杨酸盐,O,O- di-C 3 -C 8 烷基二硫代磷酸酯,C 1 -C 8 -烷基黄原酸酯,ICl 2 -,ICIBr-,IBr 2 -,Cl 3 -,Br 3 -或N,N-二烷基分子式二硫代氨基甲酸酯其中两个残基A各自为C 1 -C 8 烷基或与吡咯烷基,哌啶子基或-一起形成基团-NA 2 吗啉代残基; (Hb) 1-是阴离子(b) 2-和(b) 2的氢原子形式-表示下式的硫酸盐,碳酸盐,亚乙基-双-二硫代氨基甲酸酯 <!-EPO ->[Fe(CN) 5 (NO)] 2-,(Fe(SCN) 5 (NO)] 2 -或络合阴离子[Me(L) 4 ] 2-,其中Me代表锌,铜或镍原子,L代表氰化物或罗丹酰胺; (H 2 c) 1-和(Hc) 2-是二氢和氢形式(c) 3-的负离子,和( C 3 -的负离子表示磷酸盐[Cu(CN) 4 ] 3-,[Cu(SCN) 4 ] 3-或复合阴离子[Me 1 ( L) 6 ] 3-,其中Me'代表铁,钴或锰原子,L代表氰化物或罗丹酰胺;和 (H 3 d) 1-,(H 2 d) 2-和(Hd) 3-是阴离子(d) 4-的三氢,二氢和氢形式,(d) 4-表示络合物阴离子[ Me'(L) 6] 4 -,其中Me'代表铁,钴或锰原子,L代表氰化物或罗丹酰胺,前提是在Y = N的情况下,X n-不是N,N-二烷基二硫代氨基甲酸酯,硼酸四苯酯,硝酸盐,硫酸氢盐,硫酸盐,磷酸盐,氢或二氢进一步规定,如果Y = P且同时X n- =硼酸四苯酯,则R 1 不是苯基。

著录项

  • 公开/公告号BR9204574A

    专利类型

  • 公开/公告日1993-06-01

    原文格式PDF

  • 申请/专利权人 FMC CORPORATION (UK) LIMITED;

    申请/专利号BR19929204574

  • 发明设计人 WOLFGANG WEHNER;REINHARDT GRADE;

    申请日1992-11-26

  • 分类号C07F9/28;

  • 国家 BR

  • 入库时间 2022-08-22 05:12:31

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