首页> 外国专利> Sorption of carboxylic acid from carboxylic salt solutions at PHS close to or above the pK.sub.a of the acid, with regeneration with an aqueous solution of ammonia or low-molecular-weight alkylamine

Sorption of carboxylic acid from carboxylic salt solutions at PHS close to or above the pK.sub.a of the acid, with regeneration with an aqueous solution of ammonia or low-molecular-weight alkylamine

机译:在接近或高于酸的pKA的PHS上从羧酸盐溶液中吸附羧酸,并用氨水或低分子量烷基胺水溶液进行再生

摘要

Carboxylic acids are sorbed from aqueous feedstocks at pHs close to or above the acids' pH.sub.a into a strongly basic organic liquid phase or onto a basic solid adsorbent or moderately basic ion exchange resin. the acids are freed from the sorbent phase by treating it with aqueous alkylamine or ammonia thus forming an alkylammonium or ammonium carobxylate which dewatered and decomposed to the desired carboxylic acid and the alkylamine or ammonia.
机译:羧酸在接近或高于酸的pH值的pH值下从水性原料中吸附到强碱性有机液相中或碱性固体吸附剂或中等碱性离子交换树脂上。通过用烷基胺或氨水处理将酸从吸附剂相中分离出来,从而形成烷基铵或羧甲基铵,将其脱水并分解为所需的羧酸和烷基胺或氨。

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