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Process for making nanocrystalline metallic alloy powders by high energy mechanical alloying

机译:通过高能机械合金化制备纳米晶金属合金粉末的方法

摘要

There are described metallic powders comprising agglomerated nanocrystals of an electroactive alloy. The main component of the alloy can be of nickel, cobalt, iron or mixtures thereof while the alloying element is one or more transition metals such as Mo, W, V. Preferably the nanocrystals will be made of an alloy of nickel and molybdenum. An electrode which is used by compacting the powders is also disclosed. Also disclosed, is a process for producing the metallic powders by providing particles of nickel, cobalt and iron with particles of at least one transition metal, (Mo, W, V) and subjecting the particles to high energy mechanical alloying such as ball milling under conditions and for a sufficient period of time to produce a nanocrystalline alloy. Electrodes produced from these powders have an electrocatalytic activity for the hydrogen evolution which is comparable or higher than the electrodes which are presently used in the electrochemical industry. Moreover, these materials present an excellent chemical, electrochemical and mechanical stability.
机译:描述了包含电活性合金的团聚纳米晶体的金属粉末。合金的主要成分可以是镍,钴,铁或其混合物,而合金元素是一种或多种过渡金属,例如Mo,W,V。优选地,纳米晶体将由镍和钼的合金制成。还公开了通过压制粉末而使用的电极。还公开了一种通过向镍,钴和铁的颗粒提供至少一种过渡金属(Mo,W,V)的颗粒并使该颗粒经受高能机械合金化(例如在球磨下进行球磨)而制备金属粉末的方法。条件和足够的时间来生产纳米晶合金。由这些粉末生产的电极具有对氢析出的电催化活性,其与目前在电化学工业中使用的电极相当或更高。此外,这些材料具有出色的化学,电化学和机械稳定性。

著录项

  • 公开/公告号US5112388A

    专利类型

  • 公开/公告日1992-05-12

    原文格式PDF

  • 申请/专利权人 HYDRO-QUEBEC;

    申请/专利号US19890396677

  • 申请日1989-08-22

  • 分类号C23C10/00;B22F1/00;

  • 国家 US

  • 入库时间 2022-08-22 05:22:53

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